| Carbonyltris(triphenylphosphine)rhodium(I) hydride Basic information |
| Product Name: | Carbonyltris(triphenylphosphine)rhodium(I) hydride |
| Synonyms: | HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM (I);CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I);CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) HYDRIDE;CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRIDE;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL HYDRIDE;(betab-5-23)-rhodiu;carbonylhydrotris(triphenylphosphine)rhodium;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) & |
| CAS: | 17185-29-4 |
| MF: | 3C18H15P.CO.HRh |
| MW: | 918.8 |
| EINECS: | 241-230-3 |
| Product Categories: | metal carbonyl complexes;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Rh |
| Mol File: | 17185-29-4.mol |
| Carbonyltris(triphenylphosphine)rhodium(I) hydride Chemical Properties |
| Melting point | 150 °C (dec.) (lit.) |
| density | 1.33 |
| vapor pressure | 0Pa at 25℃ |
| storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
| solubility | Soluble in hydrocarbons (e.g. benzene and toluene) with dissociation of phosphine ligands |
| form | crystal |
| color | light yellow |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| Merck | 14,9758 |
| Exposure limits | ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 |
| InChIKey | CEKFIOLKXHVOKA-UHFFFAOYSA-N |
| CAS DataBase Reference | 17185-29-4(CAS DataBase Reference) |
| NIST Chemistry Reference | carbonyl(hydrido)tris(triphenylphosphine)rhodium(17185-29-4) |
| EPA Substance Registry System | Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)- (17185-29-4) |
| Safety Information |
| Hazard Codes | T |
| Risk Statements | 23/24/25 |
| Safety Statements | 36/37/39-45-36/37 |
| RIDADR | UN 2811 6.1/PG 2 |
| WGK Germany | 1 |
| F | 10-23 |
| TSCA | Yes |
| HazardClass | 4.3 |
| PackingGroup | III |
| HS Code | 28439000 |
| MSDS Information |
| Provider | Language |
|---|---|
| Carbonyltris(triphenylphosphine)rhodium(I) hydride | English |
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| Carbonyltris(triphenylphosphine)rhodium(I) hydride Usage And Synthesis |
| Chemical Properties | yellow crystals |
| Uses | Catalyst. |
| Uses | Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation |
| Carbonyltris(triphenylphosphine)rhodium(I) hydride Preparation Products And Raw materials |
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