(R)-2,2′-Bis-((S)-toluene-4-sulfinyl)-[1,1′]binaphthalenyl

(R)-2,2′-Bis-((S)-toluene-4-sulfinyl)-[1,1′]binaphthalenyl
  • CAS No.:722455-72-3
Other grades of this product :
(R)-2,2′-Bis-((S)-toluene-4-sulfinyl)-[1,1′]binaphthalenyl Basic information
Product Name:(R)-2,2′-Bis-((S)-toluene-4-sulfinyl)-[1,1′]binaphthalenyl
Synonyms:(1R)-2,2′-Bis[(S)-(4-methylphenyl)sulfinyl]-1,1′-binaphthalene;(M,S,S)-1,1′-Binaphthalene-2,2′-diyl-bis(p-tolylsulfoxide);(M,S,S)-pTol-BINASO;(R)-2,2′-Bis-((S)-toluene-4-sulfinyl)-[1,1′]binaphthalenyl
CAS:722455-72-3
MF:C34H26O2S2
MW:530.7
EINECS:
Product Categories:
Mol File:722455-72-3.mol
(R)-2,2′-Bis-((S)-toluene-4-sulfinyl)-[1,1′]binaphthalenyl Chemical Properties
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
MSDS Information
(R)-2,2′-Bis-((S)-toluene-4-sulfinyl)-[1,1′]binaphthalenyl Usage And Synthesis
Uses(1R)-2,2′-Bis[(S)-(4-methylphenyl)sulfinyl]-1,1′-binaphthalene (p-tolyl-BINASO) is a bis-sulfoxide ligand that can be used to prepare cationic palladium and platinum complexes. These complexes are employed as catalysts in hydroboration and diboration reactions. It can also be used to prepare the precatalyst [p-tol-BINASO}RhCl]2 for the synthesis of chiral arylcycloketones by the 1,4-addition reaction of arylboronic acids to cyclic α,β-unsaturated ketones.
(R)-2,2′-Bis-((S)-toluene-4-sulfinyl)-[1,1′]binaphthalenyl Preparation Products And Raw materials

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