(R)-(S)-BPPFA

(R)-(S)-BPPFA
  • CAS No.:74311-56-1
Other grades of this product :
(R)-(S)-BPPFA Basic information
Product Name:(R)-(S)-BPPFA
Synonyms:(R)-(S)-BPPFA;(-)-(R)-N,N-DIMETHYL-1-[(S)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE;(R)-N,N-DIMETHYL-1-[(S)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE;(-)-(R)-N,N-dimethyl-1-((S)-1',2-bis(di-phenylpho;(-)-(R)-N,N-DIMETHYL-1-((S)-1',2-BIS(DI- PHENYLPHOSPHINO)FERROCENYL)ET-AMIN,95%;(R)-N,N-Dimethyl-1-((S)-1',2-bis(diphenylphosphino;[r,r]-1-[1-dimethylaminoethyl]-1',2-bis[diphenylphosphino]ferrocene;N,N-dimethyl-1-[1,2-bis(diphenylphosphino)ferrocenyl]ethyl
CAS:74311-56-1
MF:C38H37FeNP210*
MW:625.5
EINECS:
Product Categories:Chiral Phosphine;Asymmetric Synthesis;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Phosphine Ligands;Synthetic Organic Chemistry;Transition Metal Compounds
Mol File:74311-56-1.mol
(R)-(S)-BPPFA Chemical Properties
Melting point 143-144 °C(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form solid
color Light yellow to Brown
optical activity[α]20/D 350°, c = 0.5 in chloroform
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(R)-(S)-BPPFA Usage And Synthesis
UsesLigand used in the enantioselective silylation of allylic chlorides.
Uses(-)-(R)-(S)-BPPFA is an electron-rich bulky ligand used in amination reactions of aryl halides and tosylates. Homogeneous catalyst.
(R)-(S)-BPPFA Preparation Products And Raw materials

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