| CYCLOHEXYLZINC BROMIDE Basic information |
| Product Name: | CYCLOHEXYLZINC BROMIDE |
| Synonyms: | CYCLOHEXYLZINC BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;CYCLOHEXYLZINC BROMIDE;cyclohexylzinc bromide solution;Cyclohexylzinc bromide solution 0.5 in THF;Cyclohexylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;cyclohexylzinc(II) broMide;Cyclohexylzinc broMide solution 0.5 M in THF;Cyclohexylzinc broMide, 0.5 M solution in THF, SpcSeal |
| CAS: | 7565-57-3 |
| MF: | C6H11BrZn |
| MW: | 228.45 |
| EINECS: | |
| Product Categories: | Chemical Synthesis;Organometallic Reagents;Alkyl;Organozinc Halides;Organozinc Halides;Rieke and Organozinc Reagents;Reike and Organozinc Reagents |
| Mol File: | 7565-57-3.mol |
| CYCLOHEXYLZINC BROMIDE Chemical Properties |
| Melting point | 114.0-116.0 °C |
| density | 0.963 g/mL at 25 °C |
| Fp | 3 °F |
| storage temp. | 2-8°C |
| Water Solubility | Reacts with water. |
| Sensitive | Air Sensitive |
| Exposure limits | ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)OSHA: TWA 200 ppm(590 mg/m3)NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| Safety Information |
| Hazard Codes | F,Xn,C |
| Risk Statements | 14-19-22-36/37/38-40-37-34-11 |
| Safety Statements | 16-23-26-36-45-36/37/39 |
| RIDADR | UN 2056 3/PG 2 |
| WGK Germany | 1 |
| HazardClass | 4.3 |
| HS Code | 29319090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| CYCLOHEXYLZINC BROMIDE Usage And Synthesis |
| Uses | It is used as primary and secondary intermediate. |
| Uses | Cyclohexylzinc bromide is an organozinc reagent, generally used in Negishi coupling. Examples include the cross-coupling of alkylzinc halides with aryl/heteroaryl halides using Pd-PEPPSI-IPent and nickel-catalyzed synthesis of 4-substituted coumarins.It can react with the SO2 surrogate, 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) to afford zinc sulfinate salts which can be alkylated to synthesize various useful sulfones. |
| CYCLOHEXYLZINC BROMIDE Preparation Products And Raw materials |
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