4-(Trimethylsilyl)ethynylbenzaldehyde

4-(Trimethylsilyl)ethynylbenzaldehyde
  • CAS No.:77123-57-0
Other grades of this product :
4-(Trimethylsilyl)ethynylbenzaldehyde Basic information
Product Name:4-(Trimethylsilyl)ethynylbenzaldehyde
Synonyms:4-(TRIMETHYLSILYL)ETHYNYLBENZALDEHYDE;4-[(Trimethysilyl)-ethynyl]benzaldehyde;Benzaldehyde, 4-[(triMethylsilyl)ethynyl]-;4-[(TriMethylsilyl)ethynyl]benzaldehyde 97%;4-[(TriMethylsilyl)ethynyl]benzaldehy;4-[2-(triMethylsilyl)ethynyl]benzaldehyde;4-[(trimethylsilyl)ethynyl]bezaldehyde min99%(HPLC,GC);Benzaldehyde, 4-[2-(trimethylsilyl)ethynyl]-
CAS:77123-57-0
MF:C12H14OSi
MW:202.32
EINECS:
Product Categories:Aldehydes;C10 to C21;Carbonyl Compounds
Mol File:77123-57-0.mol
4-(Trimethylsilyl)ethynylbenzaldehyde Chemical Properties
Melting point 66-70 °C(lit.)
Boiling point 262.1±32.0 °C(Predicted)
density 0.98±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
Safety Information
Hazard Codes T
WGK Germany 3
HazardClass IRRITANT
HS Code 2931900090
MSDS Information
ProviderLanguage
SigmaAldrich English
4-(Trimethylsilyl)ethynylbenzaldehyde Usage And Synthesis
Uses4-?(Trimethylsilyl)?ethynylbenzaldehyde is a useful reactant for the synthesis of acetylene-?substituted naphthalene diimides in polar solvents.
General Description4-[(Trimethylsilyl)ethynyl]benzaldehyde can be synthesized by reacting 4-bromobenzaldehyde and triphenylphosphine in anhydrous triethylamine with ethynyltrimethylsilane and then with palladium(II) acetate under argon. It can also be prepared by Sonogashira coupling reaction between 4-bromobenzaldehyde and (trimethylsilyl) ethynyl.
4-(Trimethylsilyl)ethynylbenzaldehyde Preparation Products And Raw materials
Preparation Products{2-[2-(trimethylsilyl)ethynyl]phenyl}methanol-->4-(TRIMETHYLSILYLETHYNYL)BENZYL ALCOHOL-->4-ETHYNYLBENZYL ALCOHOL 97

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