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| Phenyl trifluoromethanesulfonate Basic information |
| Product Name: | Phenyl trifluoromethanesulfonate | | Synonyms: | PHENYL TRIFLUOROMETHANESULFONATE;PHENYL TRIFLATE;Phenol triflate;Phenol trifluoromethanesulfonate;Trifluoromethanesulfonic acid phenyl ester;Trifluoromethylsulfonyloxybenzene;Trifluoromethanesulfonic Acid Phenyl Ester
Phenyl Triflate;Phenyl trifluoromethanesulfonate 98% | | CAS: | 17763-67-6 | | MF: | C7H5F3O3S | | MW: | 226.17 | | EINECS: | | Product Categories: | | Mol File: | 17763-67-6.mol |
| Phenyl trifluoromethanesulfonate Chemical Properties |
| Boiling point | 99-100 °C/60 mmHg (lit.) | | density | 1.396 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.435(lit.) | | Fp | 160 °F | | storage temp. | Inert atmosphere,Room Temperature | | form | clear liquid | | color | Colorless to Almost colorless |
| Phenyl trifluoromethanesulfonate Usage And Synthesis |
| Chemical Properties | Colorless Liquid. | | Uses | Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies:As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos.As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling.Synthesis of N-(2,6-diarylbenzoyl)anilines by diarylation of benzanilides with phenyl triflate in the presence of palladium-based catalyst.As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofuran by the arylation of 2,3-dihydrofuran. | | Preparation | Synthesis of Phenyl trifluoromethanesulfonate: The reaction of phenol (1.00 g, 10.6 mmol) with triflic anhydride as outlined in the general procedure provided phenyl trifluoromethanesulfonate as colorless oil (0.73 g, 30%).1H NMR (400 MHz, CDCl3) δ 7.50 – 7.42 (m, 2H), 7.41 – 7.36 (m, 1H), 7.32 – 7.24 (m, 2H). | | General Description | Phenyl trifluoromethanesulfonate (phenyl triflate) is an aryl fluorosulphonate. It has been synthesized by the reaction of phenol with fluorosulphonic anhydride. |
| Phenyl trifluoromethanesulfonate Preparation Products And Raw materials |
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