TIN(IV) IODIDE

TIN(IV) IODIDE
  • CAS No.:7790-47-8
Other grades of this product :
TIN(IV) IODIDE Basic information
Product Name:TIN(IV) IODIDE
Synonyms:TIN(IV) IODIDE;TIN IODIDE;STANNIC IODIDE;TIN(IV) IODIDE 95%;TIN(IV) IODIDE, 99.999%;ultradry,99.998%metalsbasis;Tin(IV)iodide,95%;Tintetraiodide
CAS:7790-47-8
MF:I4Sn
MW:626.33
EINECS:232-208-4
Product Categories:metal halide;1
Mol File:7790-47-8.mol
TIN(IV) IODIDE Chemical Properties
Melting point 144 °C
Boiling point 364 °C
density 4.47 g/mL at 25 °C(lit.)
refractive index 2.106
Fp 340°C
solubility Soluble in alcohol, benzene, carbon disulfide, chloroform and ether.
form powder
color Red
Specific Gravity4.473
Water Solubility Soluble in alcohol, benzene, CS{2}, chloroform, and ether. Decomposes in water
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Sensitive Moisture Sensitive
Merck 14,8777
Exposure limitsACGIH: TWA 2 mg/m3NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3
CAS DataBase Reference7790-47-8(CAS DataBase Reference)
EPA Substance Registry SystemStannane, tetraiodo- (7790-47-8)
Safety Information
Hazard Codes C
Risk Statements 20/21/22-34-42/43
Safety Statements 26-28-36/37/39-45
RIDADR UN 3260 8/PG 2
WGK Germany 3
RTECS XQ3675000
1-8-10-19
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 28276000
ToxicityMLD in rats (mg/kg): 200 i.v. (Kolmer)
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
TIN(IV) IODIDE Usage And Synthesis
Chemical PropertiesBrown powder
UsesTin(IV) iodide is used in the preparation of tin(IV) oxide and tin(II) oxide. It reacts with hydroiodic acid to get rare tin hexaiodide. It forms tetraiodobis triphenylphosphine tin complexes by reacting with triphenylphosphine, which finds application in toothpaste formulation. Further, it acts as analytical reagents and also used in organic synthesis.
Safety ProfilePoison by intravenous route. Strong reaction with N02Cl, (K+ S), (Na + S). When heated to decomposition it emits toxic fumes of I-. See also TIN COMPOUNDS and IODIDES.
Purification MethodsIt is recrystallised from anhydrous CHCl3, dry it under vacuum and store it in a vacuum desiccator. It sublimes at 180o.
TIN(IV) IODIDE Preparation Products And Raw materials

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