2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane
  • CAS No.:78-63-7
Other grades of this product :
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane Basic information
Product Name:2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane
Synonyms:Trigonox 101;VAROX DBPH;VAROX DBPH-50;luperox;LUPEROX 101XL;Di-tert-butyl 1,1,4,4-tetramethyltetramethylene diperoxide;2,5-DIMETHYL-2,5-BIS(TERT-BUTYLPEROXY)HEXANE;2,5-DIMETHYL-2,5-DI(T-BUTYL-PEROXY)HEXANE
CAS:78-63-7
MF:C16H34O4
MW:290.44
EINECS:201-128-1
Product Categories:Crosslinking agent and initiating agent for silicon rubber, chlorosulfonated polyethylene CSM,polyurethane(PU) and EVA;LUPEROX 101, Trigonox 101;Organics;Crossing agent , DHBP;Trigonox 101,LUPEROX 101,DHBP;Crosslinking agent, 101
Mol File:78-63-7.mol
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane Chemical Properties
Melting point 6 °C
Boiling point 55-57 °C7 mm Hg(lit.)
density 0.877 g/mL at 25 °C(lit.)
vapor pressure 0.002Pa at 20℃
refractive index n20/D 1.423(lit.)
Fp 149 °F
storage temp. 2-8°C
Water Solubility immiscible
Stability:Unstable. May contain an inhibitor. Incompatible with strong oxidizing agents, acids, reducing agents, organic materials, powdered metals.
LogP7.34 at 20℃
CAS DataBase Reference78-63-7(CAS DataBase Reference)
EPA Substance Registry System2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane (78-63-7)
Safety Information
Hazard Codes O,Xn,Xi,E
Risk Statements 8-36/37/38-7-36/38-10-41-37/38-68-38-2
Safety Statements 7-17-36/37/39-3/7-26-14A-47-14-36/37-35
RIDADR UN 3108 5.2
WGK Germany 1
RTECS MO1835000
HazardClass 5.2
PackingGroup II
HS Code 29012990
MSDS Information
ProviderLanguage
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane English
SigmaAldrich English
ACROS English
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane Usage And Synthesis
Chemical Propertiescolourless to light yellow liquid
UsesPolymerization initiator
UsesInitiates degradation of polypropylene, monomer scavenger in styrene polymerization. Free radical polymerization initiator.
General DescriptionClear, yellow liquid. also for storage and transport mixed with inert solid.
Air & Water ReactionsInsoluble in water.
Reactivity ProfilePeroxides, such as 2,5-DIMETHYL-2,5-DI-(TERT-BUTYLPEROXY)HEXANE, are good oxidizing agents. Organic compounds can ignite on contact with concentrated peroxides. Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively with peroxides. There are few chemical classes that do not at least produce heat when mixed with peroxides. Many produce explosions or generate gases (toxic and nontoxic). Generally, dilute solutions of peroxides (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion. Solutions of peroxides often become explosive when evaporated to dryness or near-dryness. Danger of explosion when dry. May explode from heat, shock, friction or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). May be ignited by heat, sparks or flames.
Flammability and ExplosibilityFlammable
Safety ProfileModerately toxic by intraperitoneal route. Combustible when exposed to heat, flames, or reducing agents. To fight fire, use water spray, foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. Used in the polymerization of styrene and in cross-linking of various grades of polyethylene. See also PEROXIDES, ORGANIC.
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane Preparation Products And Raw materials
Raw materialsHydrogen peroxide-->Nickel-->2-Methyl-2,4-pentanediol-->2,5-DIMETHYLHEXANE-2,5-DIHYDROPEROXIDE

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