PYROLIGNEOUS ACID

PYROLIGNEOUS ACID
  • CAS No.:8030-97-5
Other grades of this product :
PYROLIGNEOUS ACID Basic information
Product Name:PYROLIGNEOUS ACID
Synonyms:Pyroligneousacids;woodvinegar;FEMA 2967;PYROLIGNEOUS ACID;WOODTARS;WOODTAR;Wood vineger;Biopirol
CAS:8030-97-5
MF:unspecified
MW:0
EINECS:232-450-0
Product Categories:Alphabetical Listings;Flavors and Fragrances;O-P
Mol File:Mol File
PYROLIGNEOUS ACID Chemical Properties
Boiling point 99 °C (lit.)
density 1.08 g/mL at 25 °C (lit.)
refractive index n20/D 1.374(lit.)
FEMA 2967 | PYROLIGNEOUS ACID
Fp 112 °F
Merck 13,8093
EPA Substance Registry SystemPyroligneous acids (8030-97-5)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 10-21-36/37/38
Safety Statements 16-26-36
RIDADR UN 1993 3/PG 3
WGK Germany 3
RTECS ZD0370000
MSDS Information
ProviderLanguage
SigmaAldrich English
PYROLIGNEOUS ACID Usage And Synthesis
Chemical PropertiesCrude, yellow to red liquid. A mixture of materials from wood distillation. Crude product contains methanol, acetic acid, acetone, furfural, and various tars and related products Miscible with water and alcohol.
Chemical PropertiesPyroligneous acid is a smoke-flavoring solution. It is also referred to as liquid smoke, char-smoke flavor, wood vinegar and pyroligneous acid extract. Pyroligneous acid has a distinctive odor, an acrid smoky smell. For a detailed description of this flavoring solution, refer to Burdock (1997).
UsesLargely for smoking meats.
DefinitionPYROLIGNEOUS ACID is a volatile, complex combination obtained by the destructive distillation of wood. It may contain acetic acid, acetone, furfural, methanol and various tars.
General DescriptionA yellow to red liquid containing methyl alcohol acetic acid, acetone and other materials. Flash point below 141°F. Less dense than water. Vapors heavier than air.
Air & Water ReactionsHighly flammable. Slightly soluble in water.
Reactivity ProfilePYROLIGNEOUS ACID is a carboxylic acid. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in PYROLIGNEOUS ACID to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.
Health HazardInhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
PYROLIGNEOUS ACID Preparation Products And Raw materials
Raw materialsCREOSOTE
Preparation ProductsAcetone-->Calcium acetate-->Rum Ether

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