Other grades of this product :
| [Ru(bpz)3][PF6]2 Basic information | | Reaction |
| Product Name: | [Ru(bpz)3][PF6]2 | | Synonyms: | [Ru(bpz)3][PF6]2;[Ru(bpz)3][PF6]2 AldrichCPR;[Ru(bpz)3][PF6]2 95%;Tris (2,2'-bipyrazine) ruthenium hexafluoroborate;TRIS(2,2'-BIPYRAZINE)RUTHENIUM(II)HEXAFLUOROPHOSPHATE,95%;Tris(2,2'-bipyrazine)ruthenium(II) hexafluorophosphate, 95%;lambda2-ruthenium(2+) tris(2,2'-bipyrazine) bis(hexafluoro-lambda5-phosphanuide);2'-bipyrazine) ruthenium hexafluoroborate | | CAS: | 80907-56-8 | | MF: | C24H18F6N12PRu+ | | MW: | 720.53 | | EINECS: | | Product Categories: | | Mol File: | 80907-56-8.mol |
| [Ru(bpz)3][PF6]2 Chemical Properties |
| Melting point | 162-210°C (The MP data is a DECOMP) (lit.) | | storage temp. | Inert atmosphere,Room Temperature | | form | Powder | | color | red | | Sensitive | air sensitive |
| Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 | | TSCA | No | | HS Code | 28439000 |
| [Ru(bpz)3][PF6]2 Usage And Synthesis |
| Reaction |
- Endoperoxide synthesis by photocatalytic aerobic [2+2+2] cycloadditions.
- Aerobic oxidation of a tertiary aliphatic amine under visible-light photocatalysis. Facile synthesis of methylenebridged bis-1,3-dicarbonyl compounds.
- Hydrophosphinylation of unactivated alkenes with secondary phosphine oxides under visible-light photocatalysis.
- Photooxygenation of aryl cyclopropanes via visible light photocatalysis.
| | Uses | [Ru(bpz)3][PF6]2 may be employed as a photocatalyst during the preparation of cyclopentylamine derivatives, via visible light-assisted cycloaddition reaction of N-arylcyclopropylamines with styrene derivatives. It may also be employed for the photocatalytic synthesis of trans-substituted cyclohexene derivative. | | General Description | [Ru(bpz)3][PF6]2 can be prepared from 2-iodopyrazine. |
| [Ru(bpz)3][PF6]2 Preparation Products And Raw materials |
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![[Ru(bpz)3][PF6]2](/img/80907-56-8.jpg "[Ru(bpz)3][PF6]2")
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