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| [(S,S)-Teth-TsDpen RuCl] Basic information |
| Product Name: | [(S,S)-Teth-TsDpen RuCl] | | Synonyms: | [(S,S)-Teth-TsDPEN-RuCl], Ru 16.3%;{N-[3-(η6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-MethylbenzenesulfonylaMidato(kN -ethyl-2-aMino-(kN)]}rutheniuM(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST;[(S,S)-Teth-TsDpen RuCl];{N-[3-(·:6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-;6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-(kN)]}ruthenium(II) (S,S)-Teth-TsDpen RuCl WILLS CATALYST;(S,S)-TETH-TSDPEN RUCL WILLS CATALYST;Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS;6-phenyl)propyl]-[(1S-2S)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino- | | CAS: | 851051-43-9 | | MF: | C30H25ClN2O2RuS | | MW: | 614.12 | | EINECS: | | Product Categories: | Ru;Ru Catalysts;Catalysis and Inorganic Chemistry;Chemical Synthesis;New Products for Chemical Synthesis;Organometallic Reagents;Ruthenium | | Mol File: | 851051-43-9.mol |
| [(S,S)-Teth-TsDpen RuCl] Chemical Properties |
| Melting point | 260-268℃ | | storage temp. | 2-8°C | | form | Powder | | color | orange | | optical activity | [α]22/D +339°, c = 0.5% in chloroform | | Sensitive | Air & Moisture Sensitive |
| [(S,S)-Teth-TsDpen RuCl] Usage And Synthesis |
| Uses | Catalyst for the asymmetric transfer hydrogenation of ketones | | Uses | Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium StereoisomerC30 H31ClN2O2RuS is a catalyst for Asymmetric Transfer Hydrogenations of Ketones. | | Uses | [(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:- In the reduction of a ketone intermediate for the synthesis of esketamine.
- In asymmetric hydrogenation of acetylenic ketones.
- For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.
| | Reactions | Catalyst used for asymmetric -transfer hydrogenation.
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| [(S,S)-Teth-TsDpen RuCl] Preparation Products And Raw materials |
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![[(S,S)-Teth-TsDpen RuCl]](/img/851051-43-9.jpg "[(S,S)-Teth-TsDpen RuCl]")
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