Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane

Tris(trimethylsilyl)silyloxyethylene,  Vinyloxytris(trimethylsilyl)silane
  • CAS No.:861445-91-2
Other grades of this product :
Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Basic information
Product Name:Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane
Synonyms:Tris(trimethylsilyl)silyl vinyl ether;Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane;Trisilane, 2-(ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-;2-(Ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
CAS:861445-91-2
MF:C11H30OSi4
MW:290.7
EINECS:
Product Categories:
Mol File:861445-91-2.mol
Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Chemical Properties
Melting point 51-61 °C
Fp 78 °C
storage temp. 2-8°C
Safety Information
Hazard Codes F,Xi
Risk Statements 11-36/37/38
Safety Statements 26-36/37
RIDADR UN 1325 4.1/PG 3
MSDS Information
Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Usage And Synthesis
UsesSuper Silyl Protecting GroupsUsed for:
  • Diastereoselective [2+2] cyclizations
  • Cross-Aldol cascade reaction
  • Diastereoselective sequential reactions for generating polyols
  • Accessing distinct diastereomers and 4-component reactions
  • Supersilyl-directed aldol reactions
  • Strong electron-donating effect of the supersilyl group operates only in the α-position and not in the β-position
Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Preparation Products And Raw materials

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