Other grades of this product :
| (4R,5S)-(+)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE Basic information |
| Product Name: | (4R,5S)-(+)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE | | Synonyms: | (4R,5S)-(+)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE;(4R,5S)-4,5-Diphenyl-2-oxazolidinone;(4R,5S)-cis-4,5-Diphenyloxazolidin-2-one;(4R,5S)-(+)-cis-4,5-Diphenyl-2-oxazolidinone, ee: 98%;(4R,5S)-4,5-Diphenyl-2-oxazolidinone,99%e.e.;(4R,5S)-4,5-DIPHENYLOXAZOLIDIN-2-ONE;(4R,5S)-(+)-cis-4,5-Diphenyl-2-oxazolidinone, 98%, ee: 98%;4,5-diphenyl-2-oxazolidinone | | CAS: | 86286-50-2 | | MF: | C15H13NO2 | | MW: | 239.27 | | EINECS: | | Product Categories: | Benzene derivatives;Asymmetric Synthesis;Chiral Auxiliaries;Oxazolidinone Derivatives | | Mol File: | 86286-50-2.mol |
| (4R,5S)-(+)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE Chemical Properties |
| Melting point | 227-230 °C (lit.) | | Boiling point | 466.6±45.0 °C(Predicted) | | density | 1.192±0.06 g/cm3(Predicted) | | pka | 11.56±0.60(Predicted) | | optical activity | [α]20/D 57±4°, c = 2 in methanol |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 | | HS Code | 29029090 |
| (4R,5S)-(+)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE Usage And Synthesis |
| Chemical Properties | White powder or crystal | | Uses | Versatile chiral auxiliary for asymmetric synthesis. For a recent review, see Aldrichimica Acta . | | Preparation | To a stirred suspension of commercially available (10.0 g, 47 mmol) and triethylamine (14.4 mL, 0.10 mol) in dichloromethane (100 mL), diphosgene (3.0 mL, 25 mmol) was added dropwise at 0 °C and the mixture was stirred for 1 h at the same temperature. After concentration in vacuo, the residue was poured into water to precipitate crystals. The crystals were collected by filtration, successively washed with 10% HCl and H2O, and dried in vacuo at 50–60 °C for 3 h to afford 593a as colorless crystals (10.9 g, 97%).
|
| (4R,5S)-(+)-CIS-4,5-DIPHENYL-2-OXAZOLIDINONE Preparation Products And Raw materials |
|
日本语
한국어
Français
Deutsch
España
Türkiye