Product

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

CAS No.：864943-22-6

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(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Basic information

Product Name:	(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
Synonyms:	SF110065;(R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d;(11bS)-4-hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxidedinaphtho[ 2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide,99%e.e.;(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate
CAS:	864943-22-6
MF:	C48H29O4P
MW:	700.72
EINECS:
Product Categories:
Mol File:	864943-22-6.mol

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Chemical Properties

Melting point	390-400°C
density	1.46±0.1 g/cm3(Predicted)
storage temp.	-20°C
pka	1.11±0.20(Predicted)
optical activity	[α]22/D 44.0°, c = 1 in DMSO
CAS DataBase Reference	864943-22-6

Safety Information

WGK Germany	3
HS Code	2919900090

MSDS Information

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Usage And Synthesis

Uses

Catalyst for:

Asymmetric hydrogenation cascade
Enantioselective Friedel-Crafts reaction
Asymmetric hydrogenation of 2-substituted quinolines
Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
Asymmetric transfer hydrogenation of substituted quinoxalines

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Preparation Products And Raw materials

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