(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate

CAS No.：866641-66-9

Other grades of this product :

(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate Basic information

Reaction

Product Name:	(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate
Synonyms:	(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate;(Acetonitrile)[(biphenyl-2-yl)di-tert-butylphosphine]gold(1+) hexafluoroantimonate;2-(Di-t-butylphosphino)biphenyl(acetonitrile)gold(I) hexafluoroantiMonate, 99%;JohnPhos Au(MeCN)SbF6;(JOHNPHOS)(AUCH3CN)SBF6;2-(DI-T-BUTYLPHOSPHINO))-1,1'-BIPHENYL(ACETONITRILE)GOLD(I)HEXAFLUOROANTIMONATE,99%;2-(Di-t-butylphosphino))-1,1'-biphenyl(acetonitrile)gold(I) hexafluoroantimonate, 99%;2-(Di-t-butylphosphino)biphenyl(aceton
CAS:	866641-66-9
MF:	C22H30AuF6NPSb
MW:	0
EINECS:
Product Categories:	Au;Catalysis and Inorganic Chemistry;Chemical Synthesis;Gold Catalysis;Gold Catalysts;GoldCatalysis and Inorganic Chemistry
Mol File:	866641-66-9.mol

(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate Chemical Properties

Melting point	198-203 °C (D)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
color	white to off-white
Sensitive	air sensitive, moisture sensitive

Safety Information

Hazard Codes	Xn,N
Risk Statements	20/22-51/53
Safety Statements	61
RIDADR	UN 3077 9/PG 3
WGK Germany	3

MSDS Information

(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate Usage And Synthesis

Reaction

Gold catalyst used in the regio-and stereoselective synthesis of functionalized benzo[b]oxepines.
Gold catalyst used in the cyclization reactions of o-(buta-1,3-diyn-1-yl-)-substituted N-aryl ureas.
Gold catalyst used in the cycloisomerization of 1,7-enyne esters to structurally diverse cis-tetrahydropyridin-4-yl ketones.
Catalyst used in the synthesis of coumarin-containing natural products.
Catalyst used in the synthesis of benzo[4,5]imidazo[1,2-a]quinazolinones.

Uses

Gold Catalysts — 21st Century ′Gold Rush′

(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate Preparation Products And Raw materials

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