2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

CAS No.：898838-07-8

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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Basic information

Product Name:	2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
Synonyms:	Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium (1:1);2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution;2,2,6,6-TetraMethylpiperidinylMagnesiuM chloride lithiuM chloride coMplex solution 1.0 M in THF/toluene;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex;piperidinyL;Magnesate(1-), dichloro(2,2,6,6-tetramethylpiperidinato)-, lithium (1:1);lithium,magnesium,2,2,6,6-tetramethylpiperidin-1-ide,dichloride;Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium
CAS:	898838-07-8
MF:	C9H18Cl2LiMgN
MW:	242.4
EINECS:
Product Categories:	Chemical Synthesis;Grignard Reagents;Heteroaryl;Organometallic Reagents
Mol File:	898838-07-8.mol

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Chemical Properties

density	0.96g/mLat 25℃
Fp	-15°C
storage temp.	2-8°C

Safety Information

Hazard Codes	F,C
Risk Statements	63-11-14-19-34-37-40
Safety Statements	16-26-36/37/39-45
RIDADR	UN 3399 4.3/PG 1
WGK Germany	3
HS Code	29333990

MSDS Information

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Usage And Synthesis

Uses	2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex deprotonations using Knochel-Hauser-Base
Uses	2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride Complex is used in preparation of Pyridazinones as herbicides. Also, used in preparation of MCL-1 inhibitors useful for treatment of cancer.
Uses	2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Preparation Products And Raw materials

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