Product

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE

CAS No.：91796-57-5

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(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Basic information

Product Name:	(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE
Synonyms:	(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE;(1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE;(+)-(1S)-MENTHYL (R)-TOLUENE-4-SULFINATE;(+)-(1S)-Menthyl (R)-p-toluenesulfinate;(R)-(5S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate;(R)-(+)-MENTHYL P-TOLUENESULFINATE;(R)-(+)-P-TOLUENESULFINIC ACID D-MENTHYL ESTER;p-Toluenesulfinic acid (1R)-5β-methyl-2β-isopropylcyclohexan-1β-yl ester
CAS:	91796-57-5
MF:	C17H26O2S
MW:	294.45
EINECS:
Product Categories:	chiral;Asymmetric Synthesis;Biochemistry;Monocyclic Monoterpenes;Synthetic Organic Chemistry;Terpenes
Mol File:	91796-57-5.mol

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Chemical Properties

Melting point	104-106 °C(lit.)
refractive index	200 ° (C=2, Acetone)
storage temp.	2-8°C
form	powder to crystal
color	White to Almost white
optical activity	[α]20/D +200°, c = 2 in acetone
BRN	4907352
CAS DataBase Reference	91796-57-5(CAS DataBase Reference)

Safety Information

Safety Statements	22-24/25
WGK Germany	3

MSDS Information

Provider	Language
SigmaAldrich	English

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Usage And Synthesis

Chemical Properties	white to light yellow crystal powde
Uses	(1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate is used as a reactant in the stereoselective synthesis of pyrazole derivatives using tert-butansulfonamide as a chiral auxiliary.
Uses	(1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate can be used: As a chiral electrophile in the synthesis of fluorescent triazolopyridine ligands. To prepare various sulfinimines, which are further used in the synthesis of α-aminophosphonic acids by reacting with borane complexes. In one of the key synthetic steps for the synthesis of (S)-(+)-ethyl β-amino-3-pyridinepropanoate, a component of an antiplatelet agent.

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Preparation Products And Raw materials

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