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| Product Name: | (S,S)-2,3-Butanediol | | Synonyms: | (S-(R,R))-butane-2,3-diol;(2S,3S)-(+)-2,3-BUTANEDIOL;(2S,3S)-2,3-BUTANEDIOL;2,3-BUTANEDIOL, [S-(R*,R*)]-;L(+)-2,3-BUTANEDIOL;(S,S)-(+)-2,3-DIHYDROXYBUTANE;(S,S)-(+)-2,3-BUTANEDIOL;(S,S)-2,3-BUTANEDIOL | | CAS: | 19132-06-0 | | MF: | C4H10O2 | | MW: | 90.12 | | EINECS: | | Product Categories: | organic alcohol;Chiral Compounds;Diols;Analytical Chemistry;Chiral Building Blocks;e.e. / Absolute Configuration Determination (NMR);Enantiomer Excess & Absolute Configuration Determination;Simple Alcohols (Chiral);Synthetic Organic Chemistry;Chiral Compound;Chiral Building Blocks;Organic Building Blocks;Polyols | | Mol File: | 19132-06-0.mol |
| (S,S)-2,3-Butanediol Chemical Properties |
| Melting point | 20°C | | alpha | 13 º (c=neat) | | Boiling point | 179-182 °C (lit.) | | density | 0.987 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.433 | | Fp | 185 °F | | storage temp. | 2-8°C | | solubility | Chloroform (Slightly), Methanol (Slightly) | | pka | 14.67±0.20(Predicted) | | form | Oily Liquid | | color | Slightly yellow | | Specific Gravity | 0.987 | | PH | 9-10 (500g/l, H2O, 20℃) | | explosive limit | 3.1-11.4%(V) | | optical activity | [α]20/D +13°, neat | | Water Solubility | soluble | | BRN | 1718899 | | Stability: | hygroscopic | | CAS DataBase Reference | 19132-06-0(CAS DataBase Reference) | | NIST Chemistry Reference | 2,3-Butanediol, [S-(R*,R*)]-(19132-06-0) |
| Hazard Codes | Xi | | Safety Statements | 24/25 | | RIDADR | NA 1993 / PGIII | | WGK Germany | 3 | | HS Code | 29053995 |
| (S,S)-2,3-Butanediol Usage And Synthesis |
| Description | 2, 3-Butanediol, which is very important for a variety of chemical feedstocks and liquid fuels, can be derived from the bioconversion of natural resources1-2. It may be used in the production of antifreeze solvents, extraction solvents, butadiene, polymers, polyurethane and diacetyl and may also be used as a fuel1, 2. It can be used as a precursor in the manufacture of a range of chemical products, various plastics and pesticides, including the solvents methyl ethyl ketone (MEK), gamma-butyrolactone (GBL), and 1, 3-butadiene3. Methyl ethyl ketone can be used as a liquid fuel additive. Many other derivatives for potential uses as antifreeze agent (levo-form of 2,3 BDL), solvents, and plastic can also be prepared from 2.3-BDL. Furthermore, it can be added as a flavoring agent in food products when converted to a diacetyl by dehydrogenation2. Nowadays, it has been more and more applied of microbial fermentation for the production of 2.3-BDL2,4.
| | Reference |
- https://www.sigmaaldrich.com/catalog/product/sial/18967?lang=en®ion=US
- Lee, Jinwon, et al. "Biological production of 2,3-butanediol." Applied Microbiology & Biotechnology 55.1(2001):10-8.
- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3147483/
- Oliver, John W. K., et al. "Cyanobacterial conversion of carbon dioxide to 2, 3-butanediol. PNAS 110.4(2013):1249-1254.
| | Chemical Properties | SLIGHTLY YELLOW OILY LIQUID | | Uses | (S,S)-2,3-Butanediol is the (S,S)-isomer of 2,3-Butanediol (B690020), a naturally occurring compound found in cocoa butter. | | Definition | ChEBI: The (S,S) diastereoisomer of butane-2,3-diol. | | General Description | L-(+)-2,3-Butanediol is a stereoisomer of 2,3-Butanediol (2,3-BD). 2,3-BD may be used in the production of antifreeze solvents, extraction solvents, butadiene, polymers, polyurethane and diacetyl and may also be used as a fuel. | | Purification Methods | Purify it by fractional distillation. The bis-(4-nitrobenzoate) has m 141-142o and [] (-) or (+) 52o (c 4 CHCl3). [Ghirardelli & Lucas J Am Chem Soc 79 734 1957, Rubin et al. J Am Chem Soc 74 425 1952, Neish Can J Res 27 6 1949, Neish & Ledingham Can J Res 27 694 1949, Beilstein 1 IV 2524-2525.] |
| (S,S)-2,3-Butanediol Preparation Products And Raw materials |
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