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Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl　

CAS No.：944451-29-0

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Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl Basic information

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Product Name:	Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl
Synonyms:	Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl;(S)-RuCl[(p-cyMene)(SEGPHOS)]Cl;[RuCl(p-cymene)((S)-segphos(regR))]Cl;CHLORO[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE](P-CYMENE)RUTHENIUM(II) CHLORIDE,[RUCL(P-CYMENE)((S)-SEGPHOS;[RUCL(P-CYMENE)((S)-SEGPHOS)]CL;)]Cl;-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-segphos;Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-segphos(R))]Cl
CAS:	944451-29-0
MF:	C48H40Cl2O4P2Ru
MW:	914.76
EINECS:
Product Categories:	Ru
Mol File:	944451-29-0.mol

Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl Chemical Properties

Melting point	>100°C
storage temp.	2-8°C
Water Solubility	Insoluble in water
form	Powder
color	ocher to dark brown
Sensitive	air sensitive
CAS DataBase Reference	944451-29-0

Safety Information

WGK Germany

MSDS Information

Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl Usage And Synthesis

Reactions	Highly active highly enantioselective catalyst for hydrogenation of functionalized ketones. Slightly higher temperature is necessary to activate the cymene complexes. Asymmetric hydrogenation of α-substituted-β-alkyl-β-ketoesters accompanied by dynamic kinetic resolution.
Reactions	Organocatalyst used for the asymmetric hydrocyanation of imines. Catalyst used for enantioselective iso-Pictet-Spengler Reactions. Catalyst for multicomponent Aza-Henry Reaction
Uses	Takasago Ligands and Complexes for Asymmetric Reactions

Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl Preparation Products And Raw materials

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