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| 2,2-Diphenylacetic acid Basic information |
| 2,2-Diphenylacetic acid Chemical Properties |
| Melting point | 147-149 °C(lit.) | | Boiling point | 195°C 25mm | | density | 1,257 g/cm3 | | vapor pressure | 0.001Pa at 25℃ | | refractive index | 1.6000 (estimate) | | Fp | 195°C/25mm | | storage temp. | Sealed in dry,Room Temperature | | solubility | 0.13g/l | | form | Crystalline Powder | | pka | 3.94(at 25℃) | | color | White to creamy-white | | PH | 3.8 (H2O, 20℃)(saturated solution) | | Water Solubility | Slightly soluble in water(0.13g/L). | | Merck | 14,3316 | | BRN | 1910978 | | InChIKey | PYHXGXCGESYPCW-UHFFFAOYSA-N | | LogP | 3.17 at 25℃ | | CAS DataBase Reference | 117-34-0(CAS DataBase Reference) | | NIST Chemistry Reference | Benzeneacetic acid, «alpha»-phenyl-(117-34-0) | | EPA Substance Registry System | Benzeneacetic acid, .alpha.-phenyl- (117-34-0) |
| 2,2-Diphenylacetic acid Usage And Synthesis |
| Chemical Properties | white to creamy-white crystalline powder | | Uses | Kinetic resolution of racemic 1-heteroarylalkanols by asymmetric esterification using diphenylacetic acid with pivalic anhydride and a chiral acyl-transfer catalyst is described. Molecular crystal of acridine and diphenylacetic acid and its absolute asymmetric photodecarboxylating condensation generates chirality in a two-component. The activation parameters for the racemization of a series of ortho-alkyl-substituted diphenylacetic acids are determined. | | Definition | ChEBI: A monocarboxylic acid that is acetic acid where the methyl hydrogens have been replaced by two phenyl groups respectively. | | Synthesis Reference(s) | Journal of the American Chemical Society, 69, p. 2325, 1947 DOI: 10.1021/ja01202a023Synthetic Communications, 17, p. 1919, 1987 DOI: 10.1080/00397918708057804 | | Purification Methods | Crystallise the acid from *benzene, H2O or aqueous 50% EtOH. [Beilstein 9 H 673, 9 IV 2492.] |
| 2,2-Diphenylacetic acid Preparation Products And Raw materials |
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