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| (2S)-Bornane-10,2-sultam Basic information |
| Product Name: | (2S)-Bornane-10,2-sultam | | Synonyms: | (7aS)-8,8-Dimethylhexahydro-1H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide;(2S)-Borne-10,2-sultam;L-2,10-Camphorsultam,99%e.e.;(2S)-BORNANE-10,2-SULTAM;(1R)-(+)-2,10-CAMPHORSULTAM;(1R)-2,10-CAMPHORSULTAM;(1R,2S)-(+)-2,10-CAMPHORSULTAM;(1R,5S)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.01,5]DECANE 3,3-DIOXIDE | | CAS: | 108448-77-7 | | MF: | C10H17NO2S | | MW: | 215.31 | | EINECS: | | Product Categories: | chiral;Asymmetric Synthesis;Bicyclic Monoterpenes;Biochemistry;Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry;Terpenes;Peptide | | Mol File: | 108448-77-7.mol |
| (2S)-Bornane-10,2-sultam Chemical Properties |
| Melting point | 185-187 °C(lit.) | | alpha | 33 º (c=4.9, CHCl3) | | Boiling point | 324.8±25.0 °C(Predicted) | | density | 1.1469 (rough estimate) | | refractive index | 31 ° (C=1, CHCl3) | | storage temp. | Sealed in dry,Room Temperature | | solubility | almost transparency in Chloroform | | pka | 11.05±0.40(Predicted) | | form | powder to crystal | | color | White to Almost white | | optical activity | [α]20/D +32°, c = 5 in chloroform | | BRN | 4675755 | | InChIKey | DPJYJNYYDJOJNO-CFGJQEBVSA-N | | CAS DataBase Reference | 108448-77-7(CAS DataBase Reference) |
| (2S)-Bornane-10,2-sultam Usage And Synthesis |
| Chemical Properties | white to light yellow crystal powde | | Uses | (1R)-(+)-2,10-Camphorsultam has been used as a reactant in the synthesis of pyrrolidine acid analogs as potent dual PPARα/γ agonists. | | Purification Methods | The (-)-enantiomer is recrystallised from 95% EtOH and dried in a vacuum desiccator. It dissolves in dilute aqueous NaOH and can be precipitated without hydrolysis by acidifying. It forms the N-Na salt in EtOH (by addition of Na to the EtOH solution), and the salt can be methylated with MeI to give the (-)-N-Me lactam with m 80o after recrystallisation from hot H2O and has []D -59.6o (c 5, CHCl3) [Shriner et al. J Am Chem Soc 60 2794 1938]. [Oppolzer et al. Helv Chim Acta 69 1142 1986, Weismiller et al. Org Synth 69 154 1955, Beilstein 27 III/IV 1007.] |
| (2S)-Bornane-10,2-sultam Preparation Products And Raw materials |
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