Methyl 2-furoate

Methyl 2-furoate
  • CAS No.:611-13-2
Other grades of this product :
Methyl 2-furoate Basic information
Product Name:Methyl 2-furoate
Synonyms:RARECHEM AL BF 0007;PYROMUCIC ACID METHYL ESTER;2-(Methoxycarbonyl)furan;2-METHYLFUROATE;2-FURANCARBOXYLIC ACID METHYL ESTER;2-FUROIC ACID METHYL ESTER;METHYL 2-FURANCARBOXYLATE;METHYL 2-FUROATE
CAS:611-13-2
MF:C6H6O3
MW:126.11
EINECS:210-254-6
Product Categories:Aromatic Esters;Furan&Benzofuran;ester Flavor
Mol File:611-13-2.mol
Methyl 2-furoate Chemical Properties
Boiling point 181 °C (lit.)
density 1.179 g/mL at 25 °C (lit.)
refractive index n20/D 1.487(lit.)
FEMA 2703 | METHYL 2-FUROATE
Fp 164 °F
storage temp. Inert atmosphere,Room Temperature
form Liquid
color Clear pale yellow to brown
Odorfruity, mushroom-like odor
Water Solubility slightly soluble
Sensitive Lachrymatory
JECFA Number746
Merck 14,4307
BRN 111110
CAS DataBase Reference611-13-2(CAS DataBase Reference)
NIST Chemistry ReferenceMethyl 2-furoate(611-13-2)
EPA Substance Registry System2-Furancarboxylic acid, methyl ester (611-13-2)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 36/37/38-21/22-22
Safety Statements 26-36-36/37/39
RIDADR UN 2810 6.1/PG 3
WGK Germany 3
RTECS LV1950000
Hazard Note Irritant
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29321900
MSDS Information
ProviderLanguage
Methyl 2-furoate English
SigmaAldrich English
ACROS English
ALFA English
Methyl 2-furoate Usage And Synthesis
DescriptionMethyl 2-furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy. May be prepared from 2-furoic acid in methanol solution in the presence of HCL as catalyst (oxidation or Carmizzaro reaction).
Chemical PropertiesMethyl furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy
Chemical PropertiesColorless to light yellow liqui
OccurrenceReported found in cranberry, guava, baked potato, raisin, papaya, blackberry, baked potato, tomato, cognac, coffee, filbert, peanut, cocoa, passion fruit, almonds, tamarind, soursop, dried bonito, kiwifruit, mountain papaya, wild rice, okra, grape brandy and roasted hazelnut.
UsesSolvent, organic synthesis.
UsesMethyl 2-furoate (Methyl furan-2-carboxylate, Methyl pyromucate) was used to synthesize cis-fused 5-oxofuro[2,3-b]furans. It was also used in the preparation of sesquiterpene lactone.
PreparationFrom 2-furoic acid in methanol solution in the presence of HCl as catalyst (oxidation or Carmizzaro reaction)
Aroma threshold valuesAroma characteristics at 1.0%: musty, sweet caramel, fruity, cocoa, bready and slightly rubbery.
Taste threshold valuesTaste characteristics at 20 ppm: brothy, yeasty, caramellic and burnt with a sweet bready, acetoin, buttery nuance
Synthesis Reference(s)Chemical and Pharmaceutical Bulletin, 37, p. 3225, 1989 DOI: 10.1248/cpb.37.3225
General DescriptionMethyl 2-furoate has been identified as one of the volatile flavor compounds in tequila, okra, berrycactus and black currant juice.
Safety ProfilePoison by intraperitoneal route. A skin irritant and lachrymator. When heated to decomposition it emits acrid smoke and irritating fumes.

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