4-Bromophenylboronic acid

4-Bromophenylboronic acid
  • CAS No.:5467-74-3
Other grades of this product :
4-Bromophenylboronic acid Basic information
Product Name:4-Bromophenylboronic acid
Synonyms:AKOS BRN-0005;4-BROMOPHENYLBORIC ACID ANHYDRIDE;4-BROMOPHENYLBORONIC ACID;4-BROMOBENZENEBORONIC ACID;4-BROMOBENZENEBORONIC ACID/ANHYDRIDE;RARECHEM AH PB 0075;P-BROMO BENZENE BORONIC ACID;P-BROMOPHENYLBORONIC ACID
CAS:5467-74-3
MF:C6H6BBrO2
MW:200.83
EINECS:226-779-9
Product Categories:Boronate Ester;Potassium Trifluoroborate;Boronic acids;Boronic Acid;B (Classes of Boron Compounds);OLED materials,pharm chemical,electronic;blocks;BoronicAcids;Bromides;Boric Acid;Substituted Boronic Acids;Aryl;Halogenated;Organoborons
Mol File:5467-74-3.mol
4-Bromophenylboronic acid Chemical Properties
Melting point 284-288 °C (lit.)
Boiling point 315.0±44.0 °C(Predicted)
density 1.67±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Crystalline Powder
pka8.32±0.10(Predicted)
color Off-white to light beige
Water Solubility Soluble in methanol. Insoluble in water.
BRN 2936347
InChIKeyQBLFZIBJXUQVRF-UHFFFAOYSA-N
CAS DataBase Reference5467-74-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-22
Safety Statements 26-36-37/39
WGK Germany 3
RTECS CY8650000
TSCA T
HazardClass IRRITANT
HS Code 29319090
MSDS Information
ProviderLanguage
4-Bromobenzeneboronic acid English
SigmaAldrich English
ACROS English
ALFA English
4-Bromophenylboronic acid Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Usessuzuki reaction
Uses4-Bromobenzeneboronic acid is a reagent used for Palladium catalyzed Suzuki-Miyaura cross-couplings, Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence. It is also used in the preparation of Protein modulators and enzymatic and kinase inhibitors, Gallate-based obovatol analogs with potential anti-tumor activity. It is used as a reagent for Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes, Copper-catalyzed cross-couplings.
UsesLabelled 4-Bromophenylboronic Acid (B686545). 4-Bromophenylboric acid is used in the preparation of arylboronates as inhibitors of fatty acid amide hydrolase.

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