Product

TRIS(4-CHLOROPHENYL)PHOSPHINE

CAS No.：1159-54-2

Other grades of this product :

TRIS(4-CHLOROPHENYL)PHOSPHINE Basic information

Product Name:	TRIS(4-CHLOROPHENYL)PHOSPHINE
Synonyms:	Tri(p-chlorophenyl)phosphine,99%;TRIS(P-CHLOROPHENYL)PHOSPHINE;TRIS(4-CHLOROPHENYL)PHOSPHINE;TRI(P-CHLOROPHENYL)PHOSPHINE;TRI(4-CHLOROPHENYL)PHOSPHINE;Phosphine, tris(4-chlorophenyl)-;Phosphine, tris(p-chlorophenyl)-;1,1-dimethyl-3-(5-nitro-1,2-benzothiazol-3-yl)urea
CAS:	1159-54-2
MF:	C18H12Cl3P
MW:	365.62
EINECS:	214-596-7
Product Categories:	Achiral Phosphine;Aryl Phosphine;Ligand;Basic Phosphine LigandsCatalysis and Inorganic Chemistry;Catalysis and Inorganic Chemistry;organophosphorus ligand;Cross-Coupling;Phosphine Ligands;Phosphorus Compounds
Mol File:	1159-54-2.mol

TRIS(4-CHLOROPHENYL)PHOSPHINE Chemical Properties

Melting point	100-103 °C (lit.)
Boiling point	427.6±40.0 °C(Predicted)
storage temp.	Inert atmosphere,Room Temperature
form	crystal
color	white
Sensitive	Air Sensitive
BRN	751458
CAS DataBase Reference	1159-54-2(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-37/39
RIDADR	3278
WGK Germany	3
TSCA	No
PackingGroup	III
HS Code	29310099

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

TRIS(4-CHLOROPHENYL)PHOSPHINE Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

Catalyst for:

Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes
Solvent-free Heck reactions

Cocatalyst in:

Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents
Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes
Rhodium-catalyzed hydrogenation reactions
Platinum-catalyzed allylation reactions

TRIS(4-CHLOROPHENYL)PHOSPHINE Preparation Products And Raw materials

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