| CHLOROTITANIUM TRIISOPROPOXIDE Basic information |
| Product Name: | CHLOROTITANIUM TRIISOPROPOXIDE |
| Synonyms: | TITANIUM(IV) TRIISOPROPOXY CHLORIDE;TITANIC ACID TRIISOPROPYL ESTER CHLORIDE;TITANIUM CHLORIDE TRIISOPROPOXIDE;ORTHOTITANIC ACID TRIISOPROPYL ESTER CHLORIDE;CTT;CHLOROTRIISOPROPOXYTITANIUM;CHLOROTRIISOPROPYL ORTHOTITANATE;CHLOROTRIISOPROPYLOXYTITANE |
| CAS: | 20717-86-6 |
| MF: | C9H21ClO3Ti |
| MW: | 260.58 |
| EINECS: | 679-414-4 |
| Product Categories: | metal alkoxide;Catalysis and Inorganic Chemistry;Chemical Synthesis;Solution Deposition Precursors;Titanium;TitaniumMicro/Nanoelectronics |
| Mol File: | 20717-86-6.mol |
| CHLOROTITANIUM TRIISOPROPOXIDE Chemical Properties |
| Melting point | 35-40 °C |
| Boiling point | 63-66°C 0,1mm |
| density | 1.091 g/mL at 25 °C (lit.) |
| Fp | 72 °F |
| storage temp. | Flammables area |
| form | liquid |
| Specific Gravity | 1.091 |
| color | fused solid to pale yellow |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| Sensitive | Moisture Sensitive |
| BRN | 4163222 |
| CAS DataBase Reference | 20717-86-6(CAS DataBase Reference) |
| EPA Substance Registry System | Titanium, chlorotris(2-propanolato)-, (T-4)- (20717-86-6) |
| Safety Information |
| Hazard Codes | C,F,N |
| Risk Statements | 10-34-23/24/25-11-67-65-62-51/53-48/20 |
| Safety Statements | 26-36/37/39-45-27-16-62-61 |
| RIDADR | UN 2924 3/PG 2 |
| WGK Germany | 3 |
| F | 3-10-21 |
| TSCA | No |
| HazardClass | 4.1 |
| PackingGroup | II |
| HS Code | 29051990 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| CHLOROTITANIUM TRIISOPROPOXIDE Usage And Synthesis |
| Chemical Properties | Colorless to yellow liquid or low melting solid, |
| Uses | Chlorotriisopropoxytitanium(IV) solution may be used as a precursor for the synthesis of ultralow density ceramic materials. The product may be used to mediate a reductive amination reaction of 5α-cholestane-3,7-dione to yield aryl aminocholestanes. |
| Purification Methods | When distilled under vacuum, the distillate sets slowly to a solid on standing. Stock reagents are made by dissolving the warm liquid in pentane, toluene, Et2O, THF, CH2Cl2,, and can be stored in a pure state or in solution under dry N2 for several months. The reagent is hygroscopic and is hydrolysed by H2O. [Reetz et al. Chem Ber 118 1421 1985.] |
| CHLOROTITANIUM TRIISOPROPOXIDE Preparation Products And Raw materials |
| Raw materials | TRANS-4-CHLORO-2-PENTENE-->Titanium tetrachloride-->Allyl chloride-->Allylbenzene-->Titanium tetraisopropanolate |
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