CHLOROTITANIUM TRIISOPROPOXIDE
CHLOROTITANIUM TRIISOPROPOXIDE
  • CAS No.:20717-86-6
Other grades of this product :
CHLOROTITANIUM TRIISOPROPOXIDE Basic information
Product Name:CHLOROTITANIUM TRIISOPROPOXIDE
Synonyms:TITANIUM(IV) TRIISOPROPOXY CHLORIDE;TITANIC ACID TRIISOPROPYL ESTER CHLORIDE;TITANIUM CHLORIDE TRIISOPROPOXIDE;ORTHOTITANIC ACID TRIISOPROPYL ESTER CHLORIDE;CTT;CHLOROTRIISOPROPOXYTITANIUM;CHLOROTRIISOPROPYL ORTHOTITANATE;CHLOROTRIISOPROPYLOXYTITANE
CAS:20717-86-6
MF:C9H21ClO3Ti
MW:260.58
EINECS:679-414-4
Product Categories:metal alkoxide;Catalysis and Inorganic Chemistry;Chemical Synthesis;Solution Deposition Precursors;Titanium;TitaniumMicro/Nanoelectronics
Mol File:20717-86-6.mol
CHLOROTITANIUM TRIISOPROPOXIDE Chemical Properties
Melting point 35-40 °C
Boiling point 63-66°C 0,1mm
density 1.091 g/mL at 25 °C (lit.)
Fp 72 °F
storage temp. Flammables area
form liquid
Specific Gravity1.091
color fused solid to pale yellow
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Sensitive Moisture Sensitive
BRN 4163222
CAS DataBase Reference20717-86-6(CAS DataBase Reference)
EPA Substance Registry SystemTitanium, chlorotris(2-propanolato)-, (T-4)- (20717-86-6)
Safety Information
Hazard Codes C,F,N
Risk Statements 10-34-23/24/25-11-67-65-62-51/53-48/20
Safety Statements 26-36/37/39-45-27-16-62-61
RIDADR UN 2924 3/PG 2
WGK Germany 3
3-10-21
TSCA No
HazardClass 4.1
PackingGroup II
HS Code 29051990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
CHLOROTITANIUM TRIISOPROPOXIDE Usage And Synthesis
Chemical PropertiesColorless to yellow liquid or low melting solid,
UsesChlorotriisopropoxytitanium(IV) solution may be used as a precursor for the synthesis of ultralow density ceramic materials. The product may be used to mediate a reductive amination reaction of 5α-cholestane-3,7-dione to yield aryl aminocholestanes.
Purification MethodsWhen distilled under vacuum, the distillate sets slowly to a solid on standing. Stock reagents are made by dissolving the warm liquid in pentane, toluene, Et2O, THF, CH2Cl2,, and can be stored in a pure state or in solution under dry N2 for several months. The reagent is hygroscopic and is hydrolysed by H2O. [Reetz et al. Chem Ber 118 1421 1985.]
CHLOROTITANIUM TRIISOPROPOXIDE Preparation Products And Raw materials
Raw materialsTRANS-4-CHLORO-2-PENTENE-->Titanium tetrachloride-->Allyl chloride-->Allylbenzene-->Titanium tetraisopropanolate

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