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| Adipic dihydrazide Basic information |
| Adipic dihydrazide Chemical Properties |
| Melting point | 180-182 °C (lit.) | | Boiling point | 305.18°C (rough estimate) | | density | 1.2297 (rough estimate) | | vapor pressure | 0Pa at 25℃ | | refractive index | 1.6700 (estimate) | | Fp | 150 °C | | storage temp. | -20°C | | solubility | H2O: 100 mg/mL | | pka | 12.93±0.35(Predicted) | | form | Crystalline Powder | | color | White to slightly yellow | | Water Solubility | soluble | | BRN | 973863 | | InChIKey | IBVAQQYNSHJXBV-UHFFFAOYSA-N | | LogP | -2.7 at 20℃ | | CAS DataBase Reference | 1071-93-8(CAS DataBase Reference) | | NIST Chemistry Reference | Adipic dihydrazide(1071-93-8) | | EPA Substance Registry System | Hexanedioic acid, dihydrazide (1071-93-8) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 22-24/25 | | WGK Germany | 3 | | RTECS | AV1400000 | | Autoignition Temperature | 360 °C | | TSCA | Yes | | HazardClass | IRRITANT | | HS Code | 29280090 |
| Adipic dihydrazide Usage And Synthesis |
| Description | Adipic dihydrazide (ADH) is the most suitable hydrazide cross-linking agent, and ADH has been widely used in water-based paint emulsions in combination with diacetone acrylamide. ADH is weakly alkaline, and there is a possibility of agglomeration when solid ADH is added directly to the emulsion, so usually ADH should be dissolved in hot water before use. | | Chemical Properties | white to slightly yellow crystalline powder | | Uses | Adipic dihydrazide is used as a formaldehyde scavenger and reacts with formaldehyde, thereby preventing the volatilizing of formaldehyde in the air. It is also employed as a paint additive and coating additive. It is also used as an intermediate. Further, it is used for cross-linking water-based emulsions and as a hardener for certain epoxy resins, which finds application in powder coating. | | Uses | Adipic acid dihydrazide is a homobifunctional cross-linking reagent specific for aldehydes resulting in relatively stable hydrazone linkages. Adipic acid dihydrazide is typically, used in the linking of glycoproteins, such as antibodies, in a site specific fashion following periodate oxidation. Oxidation and coupling may conveniently be performed at pH 5.0 due to the low pKa of the hydrazide which avoids competition by primary amines. | | Flammability and Explosibility | Nonflammable |
| Adipic dihydrazide Preparation Products And Raw materials |
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