| 1,3-Bis(diphenylphosphino)propane Basic information |
| Product Name: | 1,3-Bis(diphenylphosphino)propane |
| Synonyms: | 1,3-BIS(DIPHENYLPHOSPHINE)PROPANE;1,3-BIS(DIPHENYLPHOSPHINO)PROPANE;DPPP;TRIMETHYLENEBIS(DIPHENYLPHOSPHINE);[3-(Diphenylphosphino)propyl](diphenyl)phosphine;1,3-Propanediylbis(diphenylphosphine);Bis(1,3-diphenylphosphino)propane;Phosphine, 1,3-propanediylbis[diphenyl- |
| CAS: | 6737-42-4 |
| MF: | C27H26P2 |
| MW: | 412.45 |
| EINECS: | 229-791-2 |
| Product Categories: | Phosphine Ligands;Synthetic Organic Chemistry;Ligand;API intermediates;organophosphine ligand;API intermediate;Phosphines;Achiral Phosphine;Aryl Phosphine |
| Mol File: | 6737-42-4.mol |
| 1,3-Bis(diphenylphosphino)propane Chemical Properties |
| Melting point | 63-65 °C (lit.) |
| Boiling point | 529.7±33.0 °C(Predicted) |
| Fp | 235°C |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Granules or Powder |
| color | White to light yellow-beige |
| Water Solubility | insoluble |
| Sensitive | Air Sensitive |
| BRN | 2821785 |
| InChIKey | LVEYOSJUKRVCCF-UHFFFAOYSA-N |
| CAS DataBase Reference | 6737-42-4(CAS DataBase Reference) |
| NIST Chemistry Reference | 1,3-Bis(diphenylphosphino)propane(6737-42-4) |
| EPA Substance Registry System | Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39-36 |
| WGK Germany | 3 |
| F | 10-23 |
| TSCA | Yes |
| HS Code | 29310095 |
| MSDS Information |
| Provider | Language |
|---|---|
| 1,3-Bis(diphenylphosphino)propane | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| 1,3-Bis(diphenylphosphino)propane Usage And Synthesis |
| Chemical Properties | white to light yellow crystal powde |
| Uses | suzuki reaction |
| Uses | 1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions. |
| 1,3-Bis(diphenylphosphino)propane Preparation Products And Raw materials |
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