2,3-Dihydrofuran

2,3-Dihydrofuran
  • CAS No.:1191-99-7
Other grades of this product :
2,3-Dihydrofuran Basic information
Product Name:2,3-Dihydrofuran
Synonyms:4,5-Dihydrofuran;2,3-dihydrofuran stab.;2 3-DIHYDROFURAN 99+%;2,3-DIHYDROFURANE;2,3-Dihydrofuran, 98+%;Furan, 2,3-dihydro-;2,3-Dihydrofuran,2,3-DHF;2,3-Dihydrofuran, 98+% 100GR
CAS:1191-99-7
MF:C4H6O
MW:70.09
EINECS:214-747-7
Product Categories:(intermediate of etodolac);Heterocycles, Intermediates, Metabolites & Impurities;Pyridines
Mol File:1191-99-7.mol
2,3-Dihydrofuran Chemical Properties
Melting point 280 °C(Solv: trichloroethylene (79-01-6); ethanol (64-17-5))
Boiling point 54-55 °C (lit.)
density 0.927 g/mL at 25 °C (lit.)
vapor pressure 14.46 psi ( 55 °C)
refractive index n20/D 1.423(lit.)
Fp −12 °F
storage temp. 2-8°C
form Liquid
color Clear colorless
Water Solubility slightlu soluble
BRN 103168
InChIKeyJKTCBAGSMQIFNL-UHFFFAOYSA-N
CAS DataBase Reference1191-99-7(CAS DataBase Reference)
NIST Chemistry ReferenceFuran, 2,3-dihydro-(1191-99-7)
EPA Substance Registry SystemFuran, 2,3-dihydro- (1191-99-7)
Safety Information
Hazard Codes F,Xi,Xn
Risk Statements 11-19-36-22-2017/11/19
Safety Statements 16-33-39-26-18-36
RIDADR UN 1993 3/PG 2
WGK Germany 3
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29321900
MSDS Information
ProviderLanguage
2,3-Dihydrofuran English
SigmaAldrich English
ACROS English
ALFA English
2,3-Dihydrofuran Usage And Synthesis
Chemical Propertiesclear colourless liquid
Uses2,3-Dihydrofuran is a dehydration product of tetrahydrofuran (THF). 2,3-Dihydrofuran is also used in the preparation of niologically active compounds such as antitumor agents.
Uses2,3-Dihydrofuran is a versatile reagent used in lanthanide-catalyzed Diels-Alder reactions with 2-pyrones and in Rh(II)-stabilized cycloadditions with vinylcarbenoids. It is applied for alkylation by active methylene compounds, catalyzed by trans-Dichlorobis(triphenyl-phosphine)-palladium(II). It is also used in the preparation of biologically active compounds such as antitumor agents.
General DescriptionThe enantioselective Heck arylation of 2,3-dihydrofuran with aryl iodides was studied.

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