| 1,3-Thiazole-2-carbaldehyde Basic information |
| Product Name: | 1,3-Thiazole-2-carbaldehyde |
| Synonyms: | 2-THIAZOLECARBOXALDEHYDE;2-THIAZOLECARBOXYALDEHYDE;THIAZOLE-2-CARBALDEHYDE;THIAZOLE-2-CARBOXALDEHYDE;1,3-Thiazole-2-carboxaldehyde;2-ThiazoleCarboxaldehyde(=2-FormylThiazole);2-FORMYLTHIAZOLE;1,3-THIAZOLE-2-CARBALDEHYDE |
| CAS: | 10200-59-6 |
| MF: | C4H3NOS |
| MW: | 113.14 |
| EINECS: | 688-154-0 |
| Product Categories: | Thiazole;Thiazoles, Isothiazoles & Benzothiazoles;Boronic Acid;Heterocyclic Compounds;Building Blocks;Heterocyclic Building Blocks;Aldehydes;Thiazoles, Isothiazoles &Benzothiazoles;API;Thiazoles;Building Blocks |
| Mol File: | 10200-59-6.mol |
| 1,3-Thiazole-2-carbaldehyde Chemical Properties |
| Boiling point | 61-63 °C/15 mmHg (lit.) |
| density | 1.288 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | 154 °F |
| storage temp. | 2-8°C |
| form | Liquid |
| pka | 0.44±0.10(Predicted) |
| color | Colorless to pale yellow |
| Water Solubility | soluble |
| InChIKey | ZGTFNNUASMWGTM-UHFFFAOYSA-N |
| CAS DataBase Reference | 10200-59-6(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | Xn,Xi |
| Risk Statements | 36/37/38-22 |
| Safety Statements | 36/37/39-26-23-36 |
| WGK Germany | 3 |
| Hazard Note | Harmful |
| HS Code | 29349990 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| 1,3-Thiazole-2-carbaldehyde Usage And Synthesis |
| Chemical Properties | Colorless to light yellow liqui |
| Uses | 2-Thiazolecarboxaldehyde is a useful building block for taxane analogs. |
| Synthesis Reference(s) | Synthesis, p. 998, 1987 DOI: 10.1055/s-1987-28146 |
| General Description | 2-Thiazolecarboxaldehyde is a thiazole aldehyde derivative. It undergoes Baylis–Hillman reaction with methyl acrylate catalyzed by DABCO (1,4-diazabicyclo[2.2.2]octane). The reaction mechanism has been studied by electrospray ionization mass spectrometry (ESI-MS). |
| 1,3-Thiazole-2-carbaldehyde Preparation Products And Raw materials |
| Raw materials | n-Butyllithium-->2-Aminothiazole |
| Preparation Products | 2-Cyanothiazole |
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