Methyl mercury

Methyl mercury
  • CAS No.:22967-92-6
Other grades of this product :
Methyl mercury Basic information
Product Name:Methyl mercury
Synonyms:METHYLMERCURY;Methylhydridemercury(II);Methyl mercury Standard;Methyl Mercury solution;Monomethylmercury cation;methylmercury(1+);Methyl mercury ISO 9001:2015 REACH;Mercury(1+), methyl-(9CI)
CAS:22967-92-6
MF:CH3Hg
MW:215.62
EINECS:
Product Categories:
Mol File:22967-92-6.mol
Methyl mercury Chemical Properties
EPA Substance Registry SystemMethylmercury(1+) (22967-92-6)
Safety Information
Hazardous Substances Data22967-92-6(Hazardous Substances Data)
MSDS Information
Methyl mercury Usage And Synthesis
DescriptionMuch of the notoriety of methylmercury has been generated from three separate mass poisoning events, two in Japan and one in Iraq. These events, at Minamata Bay in Niigata prefecture, and in Basra, demonstrated the potential lethality of methylmercury after it was a known toxic substance, and, though mercury is still an important risk factor for developmental toxicity, since the 1970s there have not been any large-scale poisonings of this type. Methylmercury is formed naturally in aquatic environments through the action of anaerobic bacteria on inorganic mercury.
Chemical PropertiesWater soluble, lipid soluble, high vaporpressure.
UsesOrganomercury compounds such as aryl and alkoxy-aryl have been used in medicine, agriculture, and laboratory research. Their use in medicine and in fungicides has been greatly reduced or eliminated.
DefinitionEither of two com-pounds that contain the methyl group and commonsalts of monomethylmercury.
HazardMutagen; possible carcinogen; teratogen;central nervous system poisons that easily passthrough the blood–brain barrier.
Safety ProfileA poison. An experimental teratogen. Experimental reproductive effects. Mutation data reported. Used as a fungicide. When heated to decomposition it emits toxic fumes of Hg.
Potential ExposureMethyl mercury has been used as seed disinfectants and for fungicides. It has also been used in organic synthesis.
Environmental FateInorganicmercury introduced as a pollutant into natural waters is scavenged by particulate matter and deposited into bottom sediments. Free Hg2+ is gradually released from this pool of slightly soluble inorganic mercury and is then transformed by microbial activity into methylmercury. Methylmercury diffuses into thewater column and is takenupbyfishand other organisms (either directly through water or through the food chain), and accumulated in their tissue. The degree to which mercury is transformed into methylmercury and transferred up the food chain through bioaccumulation depends on a variety of factors, including water chemistry and the complexity of the food web.
ShippingUN2025 Mercury compounds, solid, n.o.s., Hazard Class: 6.1; Labels: 6.2-Poisonous materials, Technical Name Required.
Toxicity evaluationAll mercury compounds exhibit high affinity for sulfhydryl groups in proteins. As a result, a variety of enzymes and structural proteins containing free sulfhydryl groups can be modified and their functions affected. Inhibition of protein synthesis is an early biochemical event following exposure. The integrity of the blood–brain barrier can be disrupted by methylmercury, which results in the alteration of amino acid uptake and subsequent brain metabolism. Methylmercury can alter cell division during critical stages of central nervous system (CNS) development, at least in part through inhibition of microtubule function. However, there is uncertainty whether methylmercury or the mercuric ion following cleavage from methylmercury is the ultimate toxicant.
IncompatibilitiesIncompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. May be sensitive to light.
Methyl mercury Preparation Products And Raw materials
Raw materialsMETHYLMERCURY(II) IODIDE
Preparation ProductsDIMETHYLMERCURY

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