9-Anthraldehyde

9-Anthraldehyde
  • CAS No.:642-31-9

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  1. This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
  2. This product is intended solely for non-clinical research, process development, quality studies, further chemical processing, or chemical synthesis. It must not be used in drug-product manufacturing, clinical trials, clinical diagnosis, or administration to humans or animals, or be sold, used as an input, submitted for regulatory filing, or released as an API or pharmaceutical material.
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9-Anthraldehyde Basic information
Product Name:9-Anthraldehyde
Synonyms:9-Anthrylaldehyde;9-Anthrylcarboxaldehyde;9-Formylanthracene;9-ANTHRACENECARBALDEHYDE;9-ANTHRACENECARBOXALDEHYDE;9-ANTHRALDEHYDE;AKOS B029849;AKOS BBS-00003154
CAS:642-31-9
MF:C15H10O
MW:206.24
EINECS:211-383-0
Product Categories:Aromatic Aldehydes & Derivatives (substituted);Anthracenes
Mol File:642-31-9.mol
9-Anthraldehyde Chemical Properties
Melting point 103-105 °C (lit.)
Boiling point 305.09°C (rough estimate)
density 1.0701 (rough estimate)
refractive index 1.6324 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Soluble in toluene.
form Crystalline Powder or Needles
color Yellow
Sensitive Air Sensitive
BRN 639167
Stability:Stable. Incompatible with strong bases, strong oxidizing agents.
InChIKeyYMNKUHIVVMFOFO-UHFFFAOYSA-N
CAS DataBase Reference642-31-9(CAS DataBase Reference)
NIST Chemistry Reference9-Anthracenecarboxaldehyde(642-31-9)
EPA Substance Registry System9-Anthracenecarboxaldehyde (642-31-9)
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 24/25-36
WGK Germany 3
TSCA Yes
HS Code 29122900
MSDS Information
ProviderLanguage
9-Anthracenecarboxaldehyde English
ACROS English
SigmaAldrich English
ALFA English
9-Anthraldehyde Usage And Synthesis
Chemical Propertiesyellow powder
Uses9-Anthraldehyde is used to prepare asymmetrical tridentate Schiff base ligands, 2-(9-anthrylmethyl-ideneamino)-4-methyl-phenol and functionalized ligand like 2-(anthracen-9-ylidene)-4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione through Knoevenangel condensation with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione. It is also used as an intermediate for dyes, pigment, active pharmaceutical ingredients and other organic compounds. Further, it is involved in the Diels Alder reaction with benzenediazonium-2-carboxylate.
Synthesis Reference(s)The Journal of Organic Chemistry, 53, p. 4587, 1988 DOI: 10.1021/jo00254a035
General DescriptionThe Diels-Alder reaction of 9-anthracenecarboxaldehyde with benzenediazonium-2-carboxylate was studied.
Purification Methods9-Anthraldehyde [642-31-9] M 206.2, m 104-105o. Crystallise the aldehyde from acetic acid or EtOH. [Masnori et al. J Am Chem Soc 108 1126 1986, Beilstein 7 IV 1738.]

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