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| Benzyltriphenylphosphonium chloride Basic information |
| Benzyltriphenylphosphonium chloride Chemical Properties |
| Melting point | ≥300 °C (lit.) | | density | 1.18 g/cm3 (20℃) | | vapor pressure | 0.1 hPa | | Fp | 300°C | | storage temp. | Store at <= 20°C. | | form | Crystalline Powder | | color | White to almost white | | Water Solubility | SOLUBLE | | Sensitive | Hygroscopic | | BRN | 3599868 | | Stability: | Stable. Incompatible with strong oxidizing agents. | | InChIKey | USFRYJRPHFMVBZ-UHFFFAOYSA-M | | LogP | -0.7 at 20℃ | | CAS DataBase Reference | 1100-88-5(CAS DataBase Reference) | | EPA Substance Registry System | Phosphonium, triphenyl(phenylmethyl)-, chloride (1100-88-5) |
| Hazard Codes | T,Xi | | Risk Statements | 25-36/37/38-24/25 | | Safety Statements | 26-36/37/39-45-36 | | RIDADR | UN 2811 6.1/PG 2 | | WGK Germany | 3 | | RTECS | TA2416500 | | TSCA | Yes | | HazardClass | 6.1 | | PackingGroup | II | | HS Code | 29310095 | | Toxicity | LD50 orally in Rabbit: 43 mg/kg |
| Benzyltriphenylphosphonium chloride Usage And Synthesis |
| Chemical Properties | Benzyltriphenylphosphonium Chloride is a white to off white powder, It is highly soluble in water and polarizable solvents. It is a quaternary phosphonium salt mainly used in organic synthesis as a wittig reagent and as a phase transfer catalyst in the production of fluoroelastomers and printing inks. | | Uses | Benzyltriphenylphosphonium Chloride was used as a reagent in the organic synthesis of several compounds including that of stabilised phosphonium ylides containing saturated oxygen heterocycles. Also used in the synthesis of novel substituted cis-stilbene derivatives which display antimicrobial activity. | | Application | Benzyltriphenylphosphonium chloride can be used as a reactant for the synthesis of:Platinum chloro-tetrazole complexes via azidation.Trans-stilbenes and cinnamates via Wittig olefination.Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment.Pentiptycenes for use as light-driven molecular brakes.Archipelago structures for formation of petroleum asphaltenes.It is also used as a crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites.Crosslinking agent for tube-like natural halloysite / fluorelastomer nanocompositesReactant for synthesis of:Platinum chloro tetrazole complexes via azidationTrans-stilbenes and cinnamates via Wittig olefinationAchiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatmentPentiptycenes for use as light-driven molecular brakesReactant for formation of archipelago structures for formation of petroleum asphaltenes | | Flammability and Explosibility | Notclassified | | Purification Methods | Wash it with Et2O and crystallise it from EtOH (six-sided plates). It is hygroscopic and forms crystals with one molecule of H2O. [Michaelis & Soden Justus Liebigs Ann Chem 229 320 1885, Kr.hnke Chem Ber 83 291 1950, Beilstein 16 IV 994.] |
| Benzyltriphenylphosphonium chloride Preparation Products And Raw materials |
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