Product

Tris(4-fluorophenyl)phosphine

CAS No.：18437-78-0

Other grades of this product :

Tris(4-fluorophenyl)phosphine Basic information

Product Name:	Tris(4-fluorophenyl)phosphine
Synonyms:	Phosphine, tris(p-fluorophenyl)-;TRIS(4-FLUOROPHENYL)PHOSPHINE;TRIS(P-FLUOROPHENYL)PHOSPHINE;TRI(4-FLUOROPHENYL)PHOSPHINE;Tri-(p-fluorophenyl)phosphine;Tris(4-Flurophenyl)Phosphine;Tris(4-fluorophenyl)phosphine,99%;Tris(p-fluorophenyl)phosphine,99%
CAS:	18437-78-0
MF:	C18H12F3P
MW:	316.26
EINECS:
Product Categories:	Achiral Phosphine;Aryl Phosphine;Ligand;Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds;organophosphorus ligand
Mol File:	18437-78-0.mol

Tris(4-fluorophenyl)phosphine Chemical Properties

Melting point	79-83 °C(lit.)
Boiling point	160°C/0.1mmHg(lit.)
storage temp.	Inert atmosphere,Room Temperature
form	Crystalline Powder
color	White to very slightly yellow
Water Solubility	Insoluble in water.
Sensitive	Air Sensitive
BRN	919838
InChIKey	GEPJPYNDFSOARB-UHFFFAOYSA-N
CAS DataBase Reference	18437-78-0(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
HazardClass	IRRITANT
HS Code	29319090

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English
ALFA	English

Tris(4-fluorophenyl)phosphine Usage And Synthesis

Chemical Properties	white to light yellow crystal powde
Uses	Tris(4-fluorophenyl)phosphine (TFPP) and tris(2,2,2- trifluoroethyl) phosphite (TTFP) were used as flame-retarding additives in Li-ion battery clectrolytes. Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.
Uses	Tris(4-fluorophenyl)phosphine, is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.
Uses	Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids
Preparation	with 4-bromofluorobenzene, magnesium, and phosphorous (III) trichloride.3 Alternatively, reduction of tris(4-fluorophenyl)phosphine oxide with an iron catalyst.
General Description	We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Tris(4-fluorophenyl)phosphine Preparation Products And Raw materials

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