2,3-Dimethylmaleic anhydride

2,3-Dimethylmaleic anhydride
  • CAS No.:766-39-2
Other grades of this product :
2,3-Dimethylmaleic anhydride Basic information
Product Name:2,3-Dimethylmaleic anhydride
Synonyms:2,2’-Dimethylmaleinsαureanhydrid;2,5-Furandione,3,4-dimethyl-;3,4-Dimethyl-2,5-furandione;3,4-dimethyl-2,5-furanedione;3,4-dimethyl-5-furandione;alpha,beta-Dimethylmaleic anhydride;2,3-Dimethylmaleic anhydride,97%;2,3-Dimethylmaleic anhydride ,96%
CAS:766-39-2
MF:C6H6O3
MW:126.11
EINECS:212-165-8
Product Categories:Organic Building Blocks;Heterocycles series;Carbonyl Compounds;Carboxylic Acid Anhydrides
Mol File:766-39-2.mol
2,3-Dimethylmaleic anhydride Chemical Properties
Melting point 93-96 °C (lit.)
Boiling point 223 °C (lit.)
density 1.107 g/cm3 (100℃)
refractive index 1.5627 (estimate)
Fp 222-223°C
storage temp. Store below +30°C.
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Solid
color White to Off-White
Water Solubility Soluble in ethanol, ether and chloroform. Slightly soluble in water.
Sensitive Moisture Sensitive
BRN 112044
CAS DataBase Reference766-39-2(CAS DataBase Reference)
NIST Chemistry Reference2,5-Furandione, 3,4-dimethyl-(766-39-2)
EPA Substance Registry System2,5-Furandione, 3,4-dimethyl- (766-39-2)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22
Safety Statements 45-36/37/39-28A-26
WGK Germany 3
RTECS ON4025000
9-21
TSCA Yes
HS Code 2917 19 80
Hazardous Substances Data766-39-2(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
2,3-Dimethylmaleic anhydride Usage And Synthesis
Chemical Propertieswhite to beige crystals or cryst. powder
Uses2,3-Dimethylmaleic anhydride can be usually used in the synthesis of maleimides and as an amino group protecting agent for superoxide dismutase. It is also used in the preparation of dimethylmaleic acid dimethyl ester. Further, it serves as a reactant in the dissociation of ribosomal proteins. In addition to this, The isolated molecule 2, 3-dimethylmaleic anhydride showed potent insecticidal activity in fumigation bioassay against several insect species, viz., adults of houseflies, cockroaches and stored-product insects.
DefinitionChEBI: 2,3-Dimethylmaleic anhydride is a butenolide. It is a 5-membered cyclic anhydride with a double bond between carbon atoms C2 and C3. The double bond locks the molecule in a planar conformation and stabilizes the acid anhydride against hydration. It was used as linker to a cell penetrating peptidebased nanoparticle.
Safety ProfileQuestionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes. See also ANHYDRIDES.
Purification MethodsDistil the anhydride from *benzene/ligroin and sublime in a vacuum. [Beilstein 17/11 V 69.]

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