LITHIUM TETRACHLOROCUPRATE

CAS No.：15489-27-7

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This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
This product is intended solely for non-clinical research, process development, quality studies, further chemical processing, or chemical synthesis. It must not be used in drug-product manufacturing, clinical trials, clinical diagnosis, or administration to humans or animals, or be sold, used as an input, submitted for regulatory filing, or released as an API or pharmaceutical material.
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LITHIUM TETRACHLOROCUPRATE Basic information

Product Name:	LITHIUM TETRACHLOROCUPRATE
Synonyms:	LITHIUM TETRACHLOROCUPRATE;LITHIUM TETRACHLOROCUPRATE(II);DILITHIUM TETRACHLOROCUPRATE;DI-LITHIUM TETRACHLOROCUPRATE(II);Dilithium tetrachlorocuprate(II) solution;DILITHIUM TETRACHLOROCUPRATE, 0.1M SOLUT ION IN TETRAHYDROFURAN;0.1MinTHF;Dilithium tetrachlorocuprate, 0.1 M solution in THF
CAS:	15489-27-7
MF:	Cl4CuLi2
MW:	219.24
EINECS:	203-726-8
Product Categories:	halometallate salt;Catalysis and Inorganic Chemistry;Chemical Synthesis;CopperMetal and Ceramic Science;Lithium Salts;Salts
Mol File:	15489-27-7.mol

LITHIUM TETRACHLOROCUPRATE Chemical Properties

Boiling point	66°C
density	0.91 g/mL at 25 °C
Fp	1 °F
storage temp.	Flammables area
solubility	Difficult to mix.
form	Liquid
Specific Gravity	0.91
color	Dark orange
Sensitive	Moisture Sensitive
Exposure limits	ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)OSHA: TWA 200 ppm(590 mg/m3)NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

Safety Information

Hazard Codes	F,Xi,Xn
Risk Statements	11-19-36/37-40
Safety Statements	16-29-33-46-37-36-13
RIDADR	UN 1993 3/PG 2
WGK Germany	1
F	10-21
HazardClass	3
PackingGroup	II
HS Code	28429090

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English
ALFA	English

LITHIUM TETRACHLOROCUPRATE Usage And Synthesis

Chemical Properties	clear orange to brown-red solution
Uses	Lithium tetrachlorocuprate acts as catalyst used to couple alkyl halides with alkyl Grignard reagents, Used to halogenate pyrimidine nucleosides. Organic soluble copper catalyst used in catalytic quantities to improve the efficiency of halide and allylic acetate displacements with Grignard reagent, it is used in stoichiometric amounts to open epoxides and aziridines.

LITHIUM TETRACHLOROCUPRATE Preparation Products And Raw materials

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