| LITHIUM TETRACHLOROCUPRATE Basic information |
| Product Name: | LITHIUM TETRACHLOROCUPRATE |
| Synonyms: | LITHIUM TETRACHLOROCUPRATE;LITHIUM TETRACHLOROCUPRATE(II);DILITHIUM TETRACHLOROCUPRATE;DI-LITHIUM TETRACHLOROCUPRATE(II);Dilithium tetrachlorocuprate(II) solution;DILITHIUM TETRACHLOROCUPRATE, 0.1M SOLUT ION IN TETRAHYDROFURAN;0.1MinTHF;Dilithium tetrachlorocuprate, 0.1 M solution in THF |
| CAS: | 15489-27-7 |
| MF: | Cl4CuLi2 |
| MW: | 219.24 |
| EINECS: | 203-726-8 |
| Product Categories: | halometallate salt;Catalysis and Inorganic Chemistry;Chemical Synthesis;CopperMetal and Ceramic Science;Lithium Salts;Salts |
| Mol File: | 15489-27-7.mol |
| LITHIUM TETRACHLOROCUPRATE Chemical Properties |
| Boiling point | 66°C |
| density | 0.91 g/mL at 25 °C |
| Fp | 1 °F |
| storage temp. | Flammables area |
| solubility | Difficult to mix. |
| form | Liquid |
| Specific Gravity | 0.91 |
| color | Dark orange |
| Sensitive | Moisture Sensitive |
| Exposure limits | ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)OSHA: TWA 200 ppm(590 mg/m3)NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| Safety Information |
| Hazard Codes | F,Xi,Xn |
| Risk Statements | 11-19-36/37-40 |
| Safety Statements | 16-29-33-46-37-36-13 |
| RIDADR | UN 1993 3/PG 2 |
| WGK Germany | 1 |
| F | 10-21 |
| HazardClass | 3 |
| PackingGroup | II |
| HS Code | 28429090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| LITHIUM TETRACHLOROCUPRATE Usage And Synthesis |
| Chemical Properties | clear orange to brown-red solution |
| Uses | Lithium tetrachlorocuprate acts as catalyst used to couple alkyl halides with alkyl Grignard reagents, Used to halogenate pyrimidine nucleosides. Organic soluble copper catalyst used in catalytic quantities to improve the efficiency of halide and allylic acetate displacements with Grignard reagent, it is used in stoichiometric amounts to open epoxides and aziridines. |
| LITHIUM TETRACHLOROCUPRATE Preparation Products And Raw materials |
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