BUTADIENE MONOXIDE

BUTADIENE MONOXIDE
  • CAS No.:930-22-3
Other grades of this product :
BUTADIENE MONOXIDE Basic information
Product Name:BUTADIENE MONOXIDE
Synonyms:(R,S)-2-Vinyl-oxirane;1,2-Epoxy-3-butylene;1,2-epoxybutene;1,2-Epoxybutene-3;1,2-Oxido-3-butene;1,3-Butadiene monooxide;1,3-Butadiene oxide;1,3-butadieneoxide
CAS:930-22-3
MF:C4H6O
MW:70.09
EINECS:213-210-4
Product Categories:Oxiranes;Simple 3-Membered Ring Compounds
Mol File:930-22-3.mol
BUTADIENE MONOXIDE Chemical Properties
Melting point -135 °C
Boiling point 65-66 °C(lit.)
density 0.87 g/mL at 25 °C(lit.)
refractive index n20/D 1.417(lit.)
Fp −58 °F
storage temp. 2-8°C
solubility Miscible with ethanol, ethyl ether, benzene and organic solvents.
form clear liquid to slightly cloudy liquid
color Colorless to Light orange to Yellow
Sensitive Moisture Sensitive
BRN 103170
InChIKeyGXBYFVGCMPJVJX-UHFFFAOYSA-N
CAS DataBase Reference930-22-3(CAS DataBase Reference)
EPA Substance Registry System1,2-Epoxy-3-butene (930-22-3)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-22-36
Safety Statements 16-26-36/37
RIDADR UN 1993 3/PG 2
WGK Germany 2
RTECS EM7350000
21
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29109000
Hazardous Substances Data930-22-3(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
BUTADIENE MONOXIDE Usage And Synthesis
Chemical Propertiesclear colorless to light yellow liquid
UsesButadiene monoxide is used as key starting material for the synthesis of (-)-bulgecinine and (+)-broussonetine G.
General DescriptionClear light yellow liquid.
Air & Water ReactionsHighly flammable. Water soluble.
Reactivity ProfileBUTADIENE MONOXIDE may be sensitive to heat. BUTADIENE MONOXIDE can react with oxidizing materials. . Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
Health HazardACUTE/CHRONIC HAZARDS: BUTADIENE MONOXIDE emits acrid fumes when heated to decomposition.
Fire HazardBUTADIENE MONOXIDE is flammable.
Safety ProfileA poison by intraperitoneal route. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame; can react with oxidzing materials. To fight fire, use CO2, dry chemical, water spray. When heated to decomposition it emits acrid smoke and fumes.
BUTADIENE MONOXIDE Preparation Products And Raw materials
Preparation Products1-METHOXY-2-BUTANOL-->1,6-HEPTADIEN-4-OL-->CIS-2-HEXEN-1-OL-->1,4-DICYANO-2-BUTENE-->1-cyano-2-hydroxy-3-butene

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