1,2-Difluorobenzene

1,2-Difluorobenzene
  • CAS No.:367-11-3
Other grades of this product :
1,2-Difluorobenzene Basic information
Product Name:1,2-Difluorobenzene
Synonyms:Adjacent two fluorine benzene;O-DIFLUOROBENZENE;2-Difluorobenzene;1,2-Difluorobenzene,98+%;o-Difluorobenzene,99%;1,2-Difluorobenzene 98%;1,2-Dfluorobenzene;1,2-Bifluorobenzene ,98%
CAS:367-11-3
MF:C6H4F2
MW:114.09
EINECS:206-680-7
Product Categories:Aromatic Hydrocarbons (substituted) & Derivatives;Fluorobenzene;Aryl;C6;Halogenated Hydrocarbons;Aryl Fluorinated Building Blocks;Building Blocks;Chemical Synthesis;Fluorinated Building Blocks;Halogenated Hydrocarbons;Organic Building Blocks;Organic Fluorinated Building Blocks;Other Fluorinated Organic Building Blocks;Isoquinolines ,Quinaldines ,Quinolines ,Quinazolines ,Indolines;Fluorine series;alkyl Fluorine
Mol File:367-11-3.mol
1,2-Difluorobenzene Chemical Properties
Melting point −34 °C(lit.)
Boiling point 92 °C(lit.)
density 1.158 g/mL at 25 °C(lit.)
refractive index n20/D 1.443(lit.)
Fp 36 °F
storage temp. Flammables area
solubility Chloroform, Methanol
form Liquid
Specific Gravity1.158
color Clear colorless
Water Solubility Not miscible or difficult to mix in water.
BRN 1905113
Stability:Stable. Incompatible with strong oxidizing agents. Highly flammable. Note low flash point.
CAS DataBase Reference367-11-3(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1,2-difluoro-(367-11-3)
EPA Substance Registry SystemBenzene, 1,2-difluoro- (367-11-3)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-20-2017/11/20
Safety Statements 7-16-29-33-7/9
RIDADR UN 1993 3/PG 2
WGK Germany 3
RTECS CZ5655000
Hazard Note Flammable
HazardClass 3
PackingGroup II
HS Code 29036990
MSDS Information
ProviderLanguage
1,2-Difluorobenzene English
SigmaAldrich English
ACROS English
ALFA English
1,2-Difluorobenzene Usage And Synthesis
Chemical Propertiescolourless liquid
Uses1,2-Difluorobenzene is used in electrochemical analysis of transition metal complexes. 1,2-difluorobenzene is also a potent inhibitor of NMDA receptor.
Uses1,2-Difluorobenzene(1,2-DFB) has been used to study the mechanism of dissociation of o-, m- and p-difluorobenzene ions by threshold photoelectron photoion coincidence spectroscopy. It has been used to study the room temperature adsorption of 1,2-DFB, 1,2-dichlorobenzene and 1,2-dibromobenzene on Si(100)2x1 by X-ray photoelectron spectroscopy and temperature programmed desorption. It is used as solvent in electrochemical studies on transition metal complexes. It is also applied as a solvent useful for electrochemical studies on transition metal complexes.
DefinitionChEBI: A difluorobenzene carrying fluoro groups at positions 1 and 2.
General Description1,2-Difluorobenzene undergoes defluorination under very mild conditions by H2 in the presence of NaOAc over rhodium pyridylphosphine and bipyridyl complexes tethered on a silica-supported palladium catalyst.

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