| (-)-Diisopinocampheyl chloroborane Basic information |
| Product Name: | (-)-Diisopinocampheyl chloroborane |
| Synonyms: | (-)-b-chlorodiisopinocampherylborane;(-)-diisopinocampheylchloroborane,(-)-dpc,inheptanes;(-)-diisopinocampheylchloroborane,(-)-dpc,inhexanes;(-)-BETA-CHLORODIISOPINOCAMPHEYLBORANE;(-)-B-DIISOPINOCAMPHEYL-CHLOROBORANE;(-)-B-CHLORODIISOPINOCAMPHENYLBORANE;(-)-B-CHLORODIISOPINOCAMPHEYLBORANE;(-)-DIP-CHLORIDE |
| CAS: | 85116-37-6 |
| MF: | C20H34BCl |
| MW: | 320.75 |
| EINECS: | 237-458-8 |
| Product Categories: | Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Asymmetric Synthesis;B (Classes of Boron Compounds);Boranes;Reduction;Synthetic Organic Chemistry |
| Mol File: | 85116-37-6.mol |
| (-)-Diisopinocampheyl chloroborane Chemical Properties |
| Melting point | 52-56 °C(lit.) |
| Boiling point | 66-69°C |
| density | 0.954 g/mL at 25 °C |
| refractive index | -51 ° (C=neat) |
| Fp | 82 °F |
| storage temp. | Inert atmosphere,2-8°C |
| form | clear liquid |
| color | Colorless to Almost colorless |
| BRN | 5937756 |
| CAS DataBase Reference | 85116-37-6(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | C,F+,N,F |
| Risk Statements | 34-20/22-12-10-67-65-62-51/53-48/20-50/53-11-37 |
| Safety Statements | 9-16-29-33-36/37-61-62-45-36/37/39-26 |
| RIDADR | UN 3261 8/PG 2 |
| WGK Germany | 3 |
| F | 10-21 |
| HazardClass | 3/8 |
| PackingGroup | II |
| HS Code | 29319090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| (-)-Diisopinocampheyl chloroborane Usage And Synthesis |
| Chemical Properties | solutio |
| Uses | Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols. |
| (-)-Diisopinocampheyl chloroborane Preparation Products And Raw materials |
| Raw materials | (-)-Diisopinocampheyl borane-->(1R)-(+)-ALPHA-PINENE |
| Preparation Products | (-)-ISOPINOCAMPHEYLAMINE |
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