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| DIETHYLPHOSPHONOACETIC ACID Basic information |
| DIETHYLPHOSPHONOACETIC ACID Chemical Properties |
| Boiling point | 150 °C/0.05 mmHg (lit.) | | density | 1.220 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.445(lit.) | | Fp | >230 °F | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | form | Viscous Liquid | | pka | 3.48±0.10(Predicted) | | Specific Gravity | 1.220 | | color | Clear colorless to yellow |
| DIETHYLPHOSPHONOACETIC ACID Usage And Synthesis |
| Chemical Properties | clear colorless to yellow viscous liquid | | Uses | Diethylphosphonoacetic Acid is a reagent that is used for enantioselective preparation of α-phosphoryl-α,β-unsatd.-δ-aryl-δ-lactones from nonracemic β-hydroxyaldehydes and their conversion to α-methylene-δ-aryl-δ-lactones. | | Uses | Acts as a nucleophile for nucleophilic addition reactions for synthesis of allene epoxidesReactant for: - Stereoselectivity studies of the Staudinger reaction
- Enantioselective formation of diols via epoxidation and hydration reactions
- Horner-Wadsworth-Emmons reactions
- Remote chelation controlled Ireland-Claisen rearrangement
- Ugi-Dieckmann reactions for synthesis of tetramic acid derivatives
| | Synthesis Reference(s) | Journal of the American Chemical Society, 102, p. 4534, 1980 DOI: 10.1021/ja00533a047 |
| DIETHYLPHOSPHONOACETIC ACID Preparation Products And Raw materials |
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