Product

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

CAS No.：104372-31-8

Other grades of this product :

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Basic information

Product Name:	(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
Synonyms:	(-)-(2S,8AR)-(CAMPHORSULFONYL)OXAZIRIDINE;(2S,8AR)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE;(1R)-(-)-(10-CAMPHORSULFONYL)OXAZIRIDINE;(1R)-(-)-(10-CAMPHORSULPHONYL)OXAZIRIDINE;(1R)-(-)-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(1R)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE;(R)-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(-)-((CAMPHORYL) SULFONYL)OXAZIRIDINE
CAS:	104372-31-8
MF:	C10H15NO3S
MW:	229.3
EINECS:	800-131-0
Product Categories:	Biochemistry;Oxidation;Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry;Terpenes;Intermediates & Fine Chemicals;chiral;Chiral Reagents;Asymmetric Synthesis;Bicyclic Monoterpenes;Pharmaceuticals
Mol File:	104372-31-8.mol

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Chemical Properties

Melting point	170-174 °C
alpha	-46.6 º (c=2, CHCl3 25 ºC)
Boiling point	317.6±25.0 °C(Predicted)
density	1.2486 (rough estimate)
refractive index	1.5060 (estimate)
Fp	170℃
storage temp.	2-8°C
solubility	Chloroform (Slightly), Methanol (Slightly)
pka	-11.75±0.40(Predicted)
form	Powder
color	White
optical activity	[α]20/D 44°, c = 2.2 in chloroform
BRN	6274369
CAS DataBase Reference	104372-31-8(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36-24/25
WGK Germany	3
F	10
HS Code	29349990

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Usage And Synthesis

Chemical Properties	White crystalline powder
Uses	Reactant involved in: Asymmetric synthesis of proton pump inhibitors Asymmetric synthesis of polyhydroxylated pyrrolidines Diastereoselective hydroxylation of chlorophylls a and b enolate anions Used in impregnated silica nanoparticles for removal of sulfur mustard from wastewaterUsed to modify blebbistatin for investigations of myosin inhibitor design
Uses	(1R)-(-)-(10-Camphorsulfonyl)oxaziridine is a useful synthetic intermediate. Used for asymmetric hydroxylation.

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Preparation Products And Raw materials

Raw materials

(+)-10-CAMPHORSULFONIMINE

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