Potassium methoxide

Potassium methoxide
  • CAS No.:865-33-8
Other grades of this product :
Potassium methoxide Basic information
Product Name:Potassium methoxide
Synonyms:Potassium methoxide, technical, 90%;Potassium methoxide (25% w/w solution in methanol)24-26% (CH3OK);Potassium methylate for synthesis;Potassium methoxide, 0.1 M solution in toluene/MeOH, J&KSeal;Potassium methoxide,pure,0.1 N solution in Toluene/Methanol;potassium methanolate,potassium methoxide;Methoxypotassium;Potassium methoxide, 90+%
CAS:865-33-8
MF:CH3KO
MW:70.13
EINECS:212-736-1
Product Categories:Pharmaceutical intermediates;bc0001
Mol File:865-33-8.mol
Potassium methoxide Chemical Properties
Melting point -20°C
Boiling point 84°C
density 0.95 g/mL at 20 °C
vapor pressure 0Pa at 25℃
refractive index n20/D 1.37
Fp 7°C
storage temp. Store below +30°C.
solubility Soluble in methanol and ethanol.
form Liquid
pka15.17[at 20 ℃]
color Clear colorless
Specific Gravity0.95
PH12.8 (7g/l, H2O, 20℃)
Water Solubility may decompose
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 3551544
Exposure limitsACGIH: TWA 200 ppm; STEL 250 ppm (Skin)OSHA: TWA 200 ppm(260 mg/m3)NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3)
Stability:Stable. Reacts violently with water. Moisture sensitive. Absorbs carbon dioxide from the air. Incompatible with acids, strong oxidizing agents, acid chlorides, acid anhydrides, alkali metals.
CAS DataBase Reference865-33-8(CAS DataBase Reference)
EPA Substance Registry SystemMethanol, potassium salt (865-33-8)
Safety Information
Hazard Codes F,T,C
Risk Statements 11-14-34-67-65-63-48/20-39/23/24/25-38-23/24/25
Safety Statements 8-16-26-43-45-62-46-36/37/39-33-29-25
RIDADR UN 3274 3/PG 2
WGK Germany 1
3-10-23
Autoignition Temperature30 - 50 °C
TSCA Yes
HazardClass 4.2
PackingGroup II
HS Code 29051900
MSDS Information
ProviderLanguage
Potassium methoxide English
Potassium methoxide Usage And Synthesis
Chemical Propertiessolid
UsesPotassium methoxide is used as a chemical intermediate. It is also used in biodiesel production and in fuel additives. It acts as a catalyst for the preparation of methyl formate and an alkaline catalyst for dimethyl formamide. Further, it is used as versatile reagents in chemical reactions such as condensation, esterification, alkoxylation and etherification, Claisen condensation, Wolf-Kishner reduction and Stobbe reaction.
Fire HazardFlammable solid, igniting in moist air. Rapid addition in bulk amount into halogenated solvents may cause an explosion. Reaction with arsenic pentafluoride in benzene can result in explosion (Kolditz 1965).
Flammability and ExplosibilityFlammable

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