| Azocyclotin Basic information |
| Product Name: | Azocyclotin |
| Synonyms: | AZOCYCLOTIN PESTANAL (1-(TRICYCLO- HEXYL;AZOCYCLOTIN, 250MG, NEAT;Tricyclotin;1-(tricyclohexylstannyl)-1H-1,2,4-triazole azocyclotin;1H-1,2,4-Triazole, 1-(tricyclohexylstannyl)-;azocyclotin (bsi,iso,esa);AZOCYCLOTIN STANDARD;Clermait |
| CAS: | 41083-11-8 |
| MF: | C20H35N3Sn |
| MW: | 436.22 |
| EINECS: | 255-209-1 |
| Product Categories: | INSECTICIDE;A-BPesticides&Metabolites;AR to AZ;A;AcaricidesAlphabetic;Alpha sort;Pesticides;Pesticides&Metabolites |
| Mol File: | 41083-11-8.mol |
| Azocyclotin Chemical Properties |
| Melting point | 210℃ |
| Boiling point | 487.4±28.0 °C(Predicted) |
| vapor pressure | 2×10-11 Pa (20 °C, est.) |
| storage temp. | 0-6°C |
| pka | 5.36 (weak base) |
| Water Solubility | 0.12 mg l-1 (20 °C) |
| form | neat |
| BRN | 621636 |
| CAS DataBase Reference | 41083-11-8(CAS DataBase Reference) |
| NIST Chemistry Reference | 1H-1,2,4-triazole, 1-(tricyclohexylstannyl)-(41083-11-8) |
| EPA Substance Registry System | Azocyclotin (41083-11-8) |
| Safety Information |
| Hazard Codes | T+;N,N,T+ |
| Risk Statements | 25-26-37/38-41-50/53 |
| Safety Statements | 26-28-36/37/39-38-45-60-61 |
| RIDADR | UN 2786 |
| WGK Germany | 3 |
| RTECS | WH8637700 |
| HazardClass | 6.1(a) |
| PackingGroup | I |
| Hazardous Substances Data | 41083-11-8(Hazardous Substances Data) |
| MSDS Information |
| Provider | Language |
|---|---|
| 1-(Tricyclohexylstannyl)-1H-1,2,4-triazole | English |
| Azocyclotin Usage And Synthesis |
| Uses | Azocyclotin is an organotin aracacide used in the control of mites. Azocyclotin showed weak antifeedant activity against other insects such as Spodoptera littoralis. |
| Uses | Azocyclotin is used to control all motile stages of spider mites on fruit, vines, hops, cotton, vegetables and ornamentals. |
| Definition | ChEBI: A member of the class of triazoles that is 1,2,4-triazole substituted at position 1 by a tricyclohexylstannyl group. |
| Metabolic pathway | The sedimentation of particles coated with the pesticide is relatively fast. Shortly after application of 14C-azocyclotin, distribution, solubilizing, and metabolism in fresh water microcosms begin, and azocyclotin is quickly hydrolyzed to cyhexatin (tricyclohexyltin hydroxide) by splitting of the triazole residue, and, according to the solubility of cyhexatin, cyhexatin is mainly absorbed to sediment and the layer of biota in direct contact with the sediment and further undergoes successive metabolism to result in dicyclohexyltin oxide and cyclohexyltin acid. |
| Degradation | Azocyclotin undergoes hydrolysis with DT50 values (22 °C) of 96 hours at pH 4,81 hours at pH 7 and 8 hours at pH 9 (I'M). |
| Azocyclotin Preparation Products And Raw materials |
| Raw materials | Magnesium-->Tin-->Chlorocyclohexane-->TRICYCLOHEXYLTIN CHLORIDE-->Cyhexatin |
| Preparation Products | Azocyclotin suspensoid-->Azocyclotin W.P. |
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