4-Phenyl-2-butanol
4-Phenyl-2-butanol
  • CAS No.:2344-70-9
Other grades of this product :
4-Phenyl-2-butanol Basic information
Product Name:4-Phenyl-2-butanol
Synonyms:4-Phenylbutan-2-ol;alpha-methyl-benzenepropano;AURORA KA-6974;FEMA 2879;ALPHA-METHYL-BENZENEPROPANOL;(+/-)-4-PHENYL-2-BUTANOL;4-PHENYL-2-BUTANOL;PHENYLETHYL METHYL CARBINOL
CAS:2344-70-9
MF:C10H14O
MW:150.22
EINECS:219-055-9
Product Categories:
Mol File:2344-70-9.mol
4-Phenyl-2-butanol Chemical Properties
Melting point 61 °C
Boiling point 132 °C/14 mmHg (lit.)
density 0.970 g/mL at 25 °C (lit.)
refractive index n20/D 1.5140(lit.)
FEMA 2879 | 4-PHENYL-2-BUTANOL
Fp 231 °F
storage temp. Sealed in dry,Room Temperature
pka15.10±0.20(Predicted)
form liquid
JECFA Number815
BRN 1908294
CAS DataBase Reference2344-70-9(CAS DataBase Reference)
NIST Chemistry Reference4-Phenyl-2-butanol(2344-70-9)
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 29062900
MSDS Information
ProviderLanguage
4-Phenyl-2-butanol English
SigmaAldrich English
ACROS English
4-Phenyl-2-butanol Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS LIQUID
Chemical Properties4-Phenyl-2-butanol has a herbaceous, aromatic, floral-fruity odor.
Uses4-Phenyl-2-butanol is a reagent used for the direct alkylation of amines with primary and secondary alcohols through biocatalytic hydrogen borrowing. It is also used in the preparation of personal care composition comprising malodor reduction compositions.
PreparationThe optically inactive product can be prepared by hydrogenation of benzylidene acetone in alcohol solution; under pressure in the presence of platinum oxide, palladium oxide or ferrous sulfate; by reduction with magnesium in methanol.
Synthesis Reference(s)Tetrahedron Letters, 30, p. 6461, 1989 DOI: 10.1016/S0040-4039(01)88994-2
General Description4-Phenyl-2-butanol undergoes (η5-pentaphenylcyclopentadienyl)RuCl(CO)2 catalyzed racemization efficiently at room temperature in the presence of a base. 4-Phenyl-2-butanol on reaction with sulfuric acid yields polymer.

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