P-TOLYL DISULFIDE

P-TOLYL DISULFIDE
  • CAS No.:103-19-5
Other grades of this product :
P-TOLYL DISULFIDE Basic information
Product Name:P-TOLYL DISULFIDE
Synonyms:1-Methyl-4-[(4-methylphenyl)disulfanyl]benzene;4,4’-dimethyldiphenyldisulphide;4-Methylphenyl disulfide;4-methylphenyldisulfide;Biodylon;Bis(4-methylphenyl) disulfide;bis(4-methylphenyl)disulfide;Bis(4-tolyl) disulfide
CAS:103-19-5
MF:C14H14S2
MW:246.39
EINECS:203-087-5
Product Categories:Organic Building Blocks;Sulfides/Disulfides;Sulfur Compounds
Mol File:103-19-5.mol
P-TOLYL DISULFIDE Chemical Properties
Melting point 43-46 °C (lit.)
Boiling point 349.4°C (rough estimate)
density 1.2475 (rough estimate)
refractive index 1.6210 (estimate)
Fp >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form powder to crystal
color White to Orange to Green
CAS DataBase Reference103-19-5(CAS DataBase Reference)
EPA Substance Registry SystemDisulfide, bis(4-methylphenyl) (103-19-5)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39-16
RIDADR UN 3335
WGK Germany 3
RTECS JO1526250
TSCA T
HS Code 29309090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
P-TOLYL DISULFIDE Usage And Synthesis
Chemical PropertiesCOLORLESS TO LIGHT YELLOW CRYSTALLINE SOLID
Synthesis Reference(s)The Journal of Organic Chemistry, 46, p. 2408, 1981 DOI: 10.1021/jo00324a046Tetrahedron Letters, 34, p. 903, 1993 DOI: 10.1016/S0040-4039(00)77450-8
Purification MethodsPurify it by chromatography on alumina using hexane as eluent, then crystallise it from MeOH, and/or distil it in a vacuum. [Kice & Bowers J Am Chem Soc 84 2384 1962, Beilstein 6 H 245, 6 I 212, 6 II 400, 6 III 1432, 6 IV 3206.]

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