L-ABRINE

L-ABRINE
  • CAS No.:526-31-8
Other grades of this product :
L-ABRINE Basic information
Product Name:L-ABRINE
Synonyms:H-METRP-OH;L-ABRINE;ABRINE;ABRINE, L-;N-METHYLTRYPTOPHAN;N-ME-TRP-OH;N-ME-TRP-OH HCL;N-ME-TRYPTOPHAN
CAS:526-31-8
MF:C12H14N2O2
MW:218.25
EINECS:208-388-5
Product Categories:Indoles;Tryptophans;Amino Acid Derivatives;Peptide Synthesis;Tryptophan
Mol File:526-31-8.mol
L-ABRINE Chemical Properties
Melting point >300 °C (dec.)(lit.)
alpha D21 +44° (0.28 g in 10 ml 0.5N HCl)
Boiling point 358.94°C (rough estimate)
density 1.272±0.06 g/cm3 (20 ºC 760 Torr)
refractive index 65 ° (C=1, 0.5mol/L NaOH)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pKa2.32±0.10(Predicted)
optical activity[α]20/D +65°, c = 1 in 0.5 M NaOH
Merck 14,10
BRN 86638
CAS DataBase Reference526-31-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 36
WGK Germany 3
HS Code 29339900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
L-ABRINE Usage And Synthesis
Chemical Propertieswhite to light grey crystalline powder or crystals
DefinitionChEBI: A N-methyl-L-alpha-amino acid that is the Nalpha-methyl derivative of L-tryptophan.
Biochem/physiol ActionsAn indoleamino acid that shows radical scavenging and antioxidant properties in vitro.
Purification MethodsCrystallise L-abrine from H2O or EtOH/H2O mixture and dry it for 2days at 60o in high vacuum; it has m 275-290o(dec with browning at 230o) and [] D +47.2o (c 2, 0.5N HCl) [Peter et al. Helv Chim Acta 46 577 1963]. [Gregory & Morley J Chem Soc 913 1968, Beilstein 22/14 V 40.]
L-ABRINE Preparation Products And Raw materials

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