2-Naphthaleneboronic acid

2-Naphthaleneboronic acid
  • CAS No.:32316-92-0
Other grades of this product :
2-Naphthaleneboronic acid Basic information
description Uses Solubility Application
Product Name:2-Naphthaleneboronic acid
Synonyms:AKOS BRN-0020;AKOS BRN-0041;ALPHA-NAPHTHYLBORIC ACID;1-NAPHTHYLENEBORONIC ACID;2-NAPHTHYLBORONIC ACID;2-NAPHTHENEBORONIC ACID;2-NAPHTHALENEYLBORONIC ACID;2-NAPHTHALENEBORONIC ACID
CAS:32316-92-0
MF:C10H9BO2
MW:171.99
EINECS:628-070-3
Product Categories:Boronic Acid;Naphthalene;Boron Compounds;Boronic acids;Organoborons;B (Classes of Boron Compounds);Industrial/Fine Chemicals;blocks;BoronicAcids;Boronic Acid series;OLED materials,pharm chemical,electronic;Boronate Ester;Potassium Trifluoroborate
Mol File:32316-92-0.mol
2-Naphthaleneboronic acid Chemical Properties
Melting point 269-275 °C(lit.)
Boiling point 381.9±25.0 °C(Predicted)
density 1.21±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
Water Solubility Slightly soluble in water
pka8.53±0.30(Predicted)
form Crystalline Powder and/or Chunks
color White to off-white
BRN 2936449
InChIKeyKPTRDYONBVUWPD-UHFFFAOYSA-N
CAS DataBase Reference32316-92-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
TSCA No
HazardClass IRRITANT
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
2-Naphthaleneboronic acid Usage And Synthesis
description2-Naphthalene Boronic Acid is an organometallic iridium complex with applications in catalysis and Pharmaceutical manufacturing. It can be also used in the study of an enantioselective rhodium-catalyzed addition of aryl boronic acids to 2,2,2-trifluoroacetophenones leading to chiral, tertiary trifluoromethyl alcohols.​
Uses

2-Naphthaleneboronic acid is a useful research chemical for organic synthesis and other chemical processes.

Solubility

Solubility in water: slightly soluble. Other solubilities: soluble in methanol

Application

It is used to study the enantioselective rhodium-catalyzed addition reaction of arylboronic acid and 2,2,2-trifluoroacetophenone to generate chiral tertiary trifluoromethanol.  It can also be used to study the palladium-catalyzed addition reaction of arylboronic acid and nitrile to generate aryl ketones, and aromatic adverbial clauses: palladium-catalyzed addition of oxynitrile to benzofuran.

Chemical Properties

yellow crystal powde

Usessuzuki reaction
UsesUsed in a study of an enantioselective rhodium-catalyzed addition of aryl boronic acids to 2,2,2-trifluoroacetophenones leading to chiral, tertiary trifluoromethyl alcohols. Also employed in a study of a palladium-catalyzed addition of aryl boronic acids to nitriles providing aryl ketones and to aryloxy nitriles providing benzofurans.

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