N-Acetylmorpholine

N-Acetylmorpholine
  • CAS No.:1696-20-4
Other grades of this product :
N-Acetylmorpholine Basic information
Uses
Product Name:N-Acetylmorpholine
Synonyms:N-ACETYLMORPHOLINE;MORPHOLINE, 4-ACETYL-;4-acetyl-morpholin;4-ACETYLMORPHOLINE;Acetylmorpholine;1-(4-morpholinyl)ethanone;N-1-Acetyl morpholine;N-Acetylmorfolin
CAS:1696-20-4
MF:C6H11NO2
MW:129.16
EINECS:216-913-4
Product Categories:Building Blocks;Heterocyclic Building Blocks;Morpholines
Mol File:1696-20-4.mol
N-Acetylmorpholine Chemical Properties
Melting point 14 °C (lit.)
Boiling point 240-245 °C
density 1.116 g/mL at 25 °C (lit.)
vapor pressure 2.2Pa at 20℃
refractive index n20/D 1.483(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
form clear liquid
pka-0.72±0.20(Predicted)
Specific Gravity1.116
color Colorless to Light yellow
Water Solubility MISCIBLE
BRN 111971
LogP-0.81 at 24℃
CAS DataBase Reference1696-20-4(CAS DataBase Reference)
NIST Chemistry ReferenceMorpholine, 4-acetyl-(1696-20-4)
EPA Substance Registry SystemMorpholine, 4-acetyl- (1696-20-4)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36-62-43
Safety Statements 26-36-39-36/37
WGK Germany 1
RTECS QD7000000
TSCA Yes
HS Code 29349990
MSDS Information
ProviderLanguage
4-Acetylmorpholine English
ACROS English
SigmaAldrich English
ALFA English
N-Acetylmorpholine Usage And Synthesis
UsesN-Acetylmorpholine is a very important pesticide intermediate. It is one of the main raw materials for the synthesis of agricultural fungicides enoylmorpholine and flumorpholine.
Chemical PropertiesCLEAR COLOURLESS TO VERY SLIGHTLY YELLOW LIQUID
Flammability and ExplosibilityNonflammable
Purification MethodsDistil it through an 8inch Fenske (glass helices packing, p 11) column with a manual take-off head. Purify it by fractional distillation. The hydrobromide has m 172-175o. [Brace J Am Chem Soc 75 357 1953, deBenneville et al. J Org Chem 21 1072 1956, Beilstein 27 III/IV 274.]
N-Acetylmorpholine Preparation Products And Raw materials
Raw materialsAcetic anhydride-->3-(4-Morpholinyl)propanamide-->Acrylamide
Preparation ProductsLY 294002 HYDROCHLORIDE-->SF2523-->NU7026

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