Diphenyl sulfide

Diphenyl sulfide
  • CAS No.:139-66-2
Other grades of this product :
Diphenyl sulfide Basic information
Product Name:Diphenyl sulfide
Synonyms:Diphenyl sulphide 99%;benzene sulfide;1,1’-Thiobis[benzene];1,1’-thiobis-benzen;1,1'-Thiobis(benzene);Benzene, 1,1'-thiobis-;benzene,1,1’-thiobis;Diphenyl monosulfide
CAS:139-66-2
MF:C12H10S
MW:186.27
EINECS:205-371-4
Product Categories:Diphenyl Sulfides (for High-Performance Polymer Research);Functional Materials;Building Blocks;Chemical Synthesis;Organic Building Blocks;Aromatics, Metabolites & Impurities, Sulfur & Selenium Compounds;Reagent for High-Performance Polymer Research;Sulfides/Disulfides;Sulfur Compounds
Mol File:139-66-2.mol
Diphenyl sulfide Chemical Properties
Melting point -40 °C (lit.)
Boiling point 296 °C (lit.)
density 1.113 g/mL at 20 °C (lit.)
vapor pressure 0.01 hPa (25 °C)
refractive index n20/D 1.6327(lit.)
Fp >230 °F
storage temp. Store below +30°C.
solubility Soluble in ether, benzene, carbon disulphide.
form Liquid
color Clear colorless to light yellow
Water Solubility insoluble
Sensitive Stench
Merck 14,7314
BRN 1907932
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKeyLTYMSROWYAPPGB-UHFFFAOYSA-N
LogP4.63 at 20℃
CAS DataBase Reference139-66-2(CAS DataBase Reference)
NIST Chemistry ReferenceDiphenyl sulfide(139-66-2)
EPA Substance Registry SystemDiphenyl sulfide (139-66-2)
Safety Information
Hazard Codes Xn,N
Risk Statements 22-38-50/53-36/38
Safety Statements 23-28-60-61-37/39-26
RIDADR UN 3082 9/PG 3
WGK Germany 3
RTECS SX2275000
13
Hazard Note Harmful/Stench
TSCA Yes
HS Code 2930 90 98
HazardClass 6.1
PackingGroup III
ToxicityLD50 orally in rats: 0.49 ml/kg (Smyth)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Diphenyl sulfide Usage And Synthesis
Chemical Propertiescolourless liquid
UsesDiphenyl Sulfide is an aromatic organosulfur compound. Diphenyl Sulfide is metabolite of the fungicide Edifenphos as well as a potential Impurity of Fenticonazole Nitrate (F279250).
UsesDiphenyl sulfide is used as a raw material for triaryl sulfonium photoinitiator, intermediates for agrichemicals, catalyst, metal extractants.
DefinitionChEBI: An aryl sulfide that consists of two phenyl groups connected by a sulphur atom.
Synthesis Reference(s)Chemical and Pharmaceutical Bulletin, 35, p. 1770, 1987 DOI: 10.1248/cpb.35.1770
Flammability and ExplosibilityNotclassified
Purification MethodsWash the sulfide with aqueous 5% NaOH, then water. Dry it with CaCl2, then with sodium. The sodium is filtered off, and the diphenyl sulfide is distiiled under reduced pressure. [Beilstein 2 H 299, 6 IV 1488.]

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