1,6-HEPTADIYNE

1,6-HEPTADIYNE
  • CAS No.:2396-63-6
Other grades of this product :
1,6-HEPTADIYNE Basic information
Product Name:1,6-HEPTADIYNE
Synonyms:1,6-HEPTADIYNE, 97%1,6-HEPTADIYNE, 97%1,6-HEPTADIYNE, 97%1,6-HEPTADIYNE, 97%;1,6-HEPTADIYNE 98%;1,6-Heptadiyne, 97+%;1,6-Heptadiyne (6CI, 8CI, 9CI);Heptane-1,6-diyne;1,6-Heptadiyne,98%;1,6-HEPTADIYNE;1,6-Heptadiyne&gt
CAS:2396-63-6
MF:C7H8
MW:92.14
EINECS:219-253-5
Product Categories:Industrial/Fine Chemicals;Acetylenes;Acetylenic Hydrocarbons;Alkynes;Organic Building Blocks;Terminal
Mol File:2396-63-6.mol
1,6-HEPTADIYNE Chemical Properties
Melting point -85 °C
Boiling point 111.5 °C (lit.)
density 0.805 g/mL at 25 °C (lit.)
refractive index n20/D 1.441(lit.)
Fp 49 °F
storage temp. 2-8°C
form Liquid
Specific Gravity0.805
color Clear yellow
Water Solubility Insoluble in water.
BRN 1731756
CAS DataBase Reference2396-63-6(CAS DataBase Reference)
EPA Substance Registry System1,6-Heptadiyne (2396-63-6)
Safety Information
Hazard Codes F
Risk Statements 11
Safety Statements 16-29-33
RIDADR UN 3295 3/PG 2
WGK Germany 2
RTECS MI5600000
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29012990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
1,6-HEPTADIYNE Usage And Synthesis
Chemical Propertiesclear yellow liquid
Uses1,6-Heptadiyne may be used in the preparation of free-standing polymer films of poly(1,6-heptadiyne). Polymerization of 1,6-heptadiyne using an insoluble Zeigler-Natta catalyst affords soluble polymer having six-membered ring containing polyene. Ruthenium(II)-catalyzed reaction of a substituted 1,6-heptadiyne with norbornene affords a tandem [2+ 2+ 2]/[4+2] cycloaddition product and a [2+ 2+2] cycloadduct.
Uses1,6-Heptadiyne may be used in the preparation of free-standing polymer films of poly(1,6-heptadiyne).
General DescriptionPolymerization of 1,6-heptadiyne using an insoluble Zeigler-Natta catalyst affords soluble polymer having six-membered ring containing polyene. Ruthenium(II)-catalyzed reaction of a substituted 1,6-heptadiyne with norbornene affords a tandem [2+ 2+ 2]/[4+2] cycloaddition product and a [2+ 2+2] cycloadduct. Cyclocopolymerization of 1,6-heptadiyne with dipropargyl ether under nitrogen atmosphere using KSCN, KBr and KI as initiators in N,N-dimethyl formamide has been studied.
1,6-HEPTADIYNE Preparation Products And Raw materials
Raw materialsSODIUM ACETYLIDE-->1,3-Dibromopropane-->Acetylene-->Ammonia
Preparation Products3-Methyl-2-cyclohexen-1-one-->2,6-HEPTANEDIONE

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