4-Bromobenzyl alcohol
4-Bromobenzyl alcohol
  • CAS No.:873-75-6
Other grades of this product :
4-Bromobenzyl alcohol Basic information
Product Name:4-Bromobenzyl alcohol
Synonyms:4-BROMOBENZYL ALCOHOL;RARECHEM AL BD 0075;P-BROMOBENZYL ALCOHOL;(4-Bromophenyl)methanol;Benzyl alcohol, p-bromo-;4-Brom-benzyl alcohol;Brombenzylalcohol;Benzenemethanol, 4-bromo-
CAS:873-75-6
MF:C7H7BrO
MW:187.03
EINECS:212-851-7
Product Categories:Oxygen Compounds;Benzhydrols, Benzyl & Special Alcohols;Alcohol;Alcohols;Bromine Compounds;C7 to C8
Mol File:873-75-6.mol
4-Bromobenzyl alcohol Chemical Properties
Melting point 75-77 °C (lit.)
Boiling point 220.79°C (rough estimate)
density 1.3839 (rough estimate)
vapor pressure 0.083Pa at 20℃
refractive index 1.5840 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility dioxane: soluble1g/10 mL, clear to faintly turbid, colorless to faintly yellow
pka14.16±0.10(Predicted)
form Crystals or Crystalline Powder
color White to slightly beige
Water Solubility 2.31g/L at 20℃
BRN 1931620
InChIKeyVEDDBHYQWFOITD-UHFFFAOYSA-N
LogP1.59 at 20℃
CAS DataBase Reference873-75-6(CAS DataBase Reference)
NIST Chemistry ReferenceBenzenemethanol, 4-bromo-(873-75-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 24/25
WGK Germany 3
Hazard Note Irritant
HS Code 29062990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
4-Bromobenzyl alcohol Usage And Synthesis
Chemical PropertiesWHITE TO SLIGHTLY BEIGE CRYSTALS OR CRYST. POWDER
Uses4-Bromobenzyl alcohol was used in the synthesis of:
  • hydroxyl end functionalized, substituted polyfluorene
  • amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)
Synthesis Reference(s)The Journal of Organic Chemistry, 48, p. 3074, 1983 DOI: 10.1021/jo00166a029Tetrahedron Letters, 36, p. 3169, 1995 DOI: 10.1016/0040-4039(95)00504-6
General Description4-Bromobenzyl alcohol undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls. It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde. It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.
Flammability and ExplosibilityNotclassified

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